Crystal structure of sodium cyclodinitridoimidodisulfophosphate dihydrate
Journal Article
·
· Sov. J. Coordinat. Chem.; (United States)
OSTI ID:6370933
An x-ray structural investigation of the sodium salt with a heterocyclic anion containing P, N, and S atoms Na3HN3S2PO6 x 2H2O has been carried out (lambdaMo, 2485 reflections, anisotropic least-squares method to R = 0.043). The crystals are monoclinic: a = 7.832(2), b = 9.954(3), c = 13.281(4) A, US = 91.06, Z = 4, space group P21/n. The structure is built up from cyclic (H3S2PO4)T anions, Na cations, and molecules of water of crystallization. The heterocycle has a chair conformation and exists in the dinitridoimido tautomeric form, and the proton is located at a nitrogen atom positioned between a sulfur atom and the phosphorus atom.
- Research Organization:
- N.S. Kurnakov Institute of General and Inorganic Chemistry, USSR
- OSTI ID:
- 6370933
- Journal Information:
- Sov. J. Coordinat. Chem.; (United States), Vol. 12:6; Other Information: Translated from Koordinatsionnaya Khimiya; 12: No.6, 840-845(Jun 1986)
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
36 MATERIALS SCIENCE
SODIUM COMPLEXES
CATALYTIC EFFECTS
MOLECULAR STRUCTURE
MONOCLINIC LATTICES
X-RAY DIFFRACTION
BINDING ENERGY
BOND ANGLE
BOND LENGTHS
COMPUTERIZED SIMULATION
ELECTRON DENSITY
ELECTRONIC STRUCTURE
ELECTRONS
HYDRATES
HYDROLYSIS
INTERATOMIC DISTANCES
ISOMERIZATION
LATTICE PARAMETERS
LEAST SQUARE FIT
NITROGEN COMPOUNDS
SODIUM PHOSPHATES
SPACE GROUPS
STRUCTURAL CHEMICAL ANALYSIS
VALENCE
ALKALI METAL COMPLEXES
ALKALI METAL COMPOUNDS
CHEMICAL REACTIONS
COHERENT SCATTERING
COMPLEXES
CRYSTAL LATTICES
CRYSTAL STRUCTURE
DECOMPOSITION
DIFFRACTION
DIMENSIONS
DISTANCE
ELEMENTARY PARTICLES
ENERGY
FERMIONS
LENGTH
LEPTONS
LYSIS
MAXIMUM-LIKELIHOOD FIT
NUMERICAL SOLUTION
OXYGEN COMPOUNDS
PHOSPHATES
PHOSPHORUS COMPOUNDS
SCATTERING
SIMULATION
SODIUM COMPOUNDS
SOLVOLYSIS
400201* - Chemical & Physicochemical Properties
360602 - Other Materials- Structure & Phase Studies
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
36 MATERIALS SCIENCE
SODIUM COMPLEXES
CATALYTIC EFFECTS
MOLECULAR STRUCTURE
MONOCLINIC LATTICES
X-RAY DIFFRACTION
BINDING ENERGY
BOND ANGLE
BOND LENGTHS
COMPUTERIZED SIMULATION
ELECTRON DENSITY
ELECTRONIC STRUCTURE
ELECTRONS
HYDRATES
HYDROLYSIS
INTERATOMIC DISTANCES
ISOMERIZATION
LATTICE PARAMETERS
LEAST SQUARE FIT
NITROGEN COMPOUNDS
SODIUM PHOSPHATES
SPACE GROUPS
STRUCTURAL CHEMICAL ANALYSIS
VALENCE
ALKALI METAL COMPLEXES
ALKALI METAL COMPOUNDS
CHEMICAL REACTIONS
COHERENT SCATTERING
COMPLEXES
CRYSTAL LATTICES
CRYSTAL STRUCTURE
DECOMPOSITION
DIFFRACTION
DIMENSIONS
DISTANCE
ELEMENTARY PARTICLES
ENERGY
FERMIONS
LENGTH
LEPTONS
LYSIS
MAXIMUM-LIKELIHOOD FIT
NUMERICAL SOLUTION
OXYGEN COMPOUNDS
PHOSPHATES
PHOSPHORUS COMPOUNDS
SCATTERING
SIMULATION
SODIUM COMPOUNDS
SOLVOLYSIS
400201* - Chemical & Physicochemical Properties
360602 - Other Materials- Structure & Phase Studies