Fast atom bombardment mass spectrometry/mass spectrometry of cationic technetium and iron complexes

Journal Article · Thu Mar 01 00:00:00 EST 1984 · Anal. Chem.; (United States)

DOI:https://doi.org/10.1021/ac00267a014· OSTI ID:6355379

Unger, S E

A series of related technetium and iron cationic complexes were examined by mass spectrometry/mass spectrometry (MS/MS). Fast atom bombardment (FAB) was used to generate secondary ions of the transition-metal complexes. Distinguishing structural characteristics were evident in their MS/MS spectra, including the site of oxidation and the relative stability to ligand dissociation. Comparison of the relative daughter ion intensities indicates structural features controlling unimolecular dissociation. 37 references, 6 figures, 3 tables.

• Research Organization: Squibb Inst. for Medical Research, Princeton, NJ
• OSTI ID: 6355379
• Journal Information: Anal. Chem.; (United States), Vol. 56:3
• Country of Publication: United States
• Language: English

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
IRON COMPLEXES
MASS SPECTROSCOPY
TECHNETIUM COMPLEXES
CATIONS
CHELATES
DISSOCIATION ENERGY
EXPERIMENTAL DATA
LIGANDS
MIXTURES
OXIDATION
REACTION KINETICS
STRUCTURAL CHEMICAL ANALYSIS
CHARGED PARTICLES
CHEMICAL REACTIONS
COMPLEXES
DATA
DISPERSIONS
ENERGY
INFORMATION
IONS
KINETICS
NUMERICAL DATA
SPECTROSCOPY
TRANSITION ELEMENT COMPLEXES
400702* - Radiochemistry & Nuclear Chemistry- Properties of Radioactive Materials
400104 - Spectral Procedures- (-1987)
400201 - Chemical & Physicochemical Properties