Photoinitiated charge transfer and dissociation in mass-selected metalloorganic complexes
Journal Article
·
· Journal of Physical Chemistry; (USA)
- Univ. of Georgia, Athens (USA)
Metalloorganic ion-molecule complexes of silver and aluminum ions with benzene and acetone molecules are prepared in a supersonic molecular beam with pulsed laser vaporization. Complexes are mass-selected in a reflectron time-of-flight spectrometer and excited with ultraviolet laser radiation in the 385-266-nm region. Aluminum complexes dissociate to produce the isolated metal ion and a neutral organic, while silver complexes undergo dissociative charge transfer, yielding charged organic fragments and neutral metal atoms. The mechanism and energetics of this new photochemistry are discussed.
- OSTI ID:
- 6329441
- Journal Information:
- Journal of Physical Chemistry; (USA), Vol. 94:12; ISSN 0022-3654
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ORGANOMETALLIC COMPOUNDS
DISSOCIATION
PHOTOCHEMISTRY
ALUMINIUM
CHARGE TRANSPORT
DATA ANALYSIS
EXPERIMENTAL DATA
MEASURING INSTRUMENTS
MEASURING METHODS
SILVER
CHEMISTRY
DATA
ELEMENTS
INFORMATION
METALS
NUMERICAL DATA
ORGANIC COMPOUNDS
TRANSITION ELEMENTS
400500* - Photochemistry
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ORGANOMETALLIC COMPOUNDS
DISSOCIATION
PHOTOCHEMISTRY
ALUMINIUM
CHARGE TRANSPORT
DATA ANALYSIS
EXPERIMENTAL DATA
MEASURING INSTRUMENTS
MEASURING METHODS
SILVER
CHEMISTRY
DATA
ELEMENTS
INFORMATION
METALS
NUMERICAL DATA
ORGANIC COMPOUNDS
TRANSITION ELEMENTS
400500* - Photochemistry