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Title: Dehydration of cyclohexanol on aluminum-chromium and aluminum-molybdenum catalysts

Abstract

The purpose of this work was to investigate the activity of chromium and molybdenum oxides deposited on ..gamma..-Al/sub 2/O/sub 3/ in the conversion reaction of cyclohexanol. The authors established that chromium oxide deposited on aluminum oxide has a high activity in the dehydration reaction of cyclohexanol. The yield of ketone reached 95 mole %. They showed that Al-Mo catalysts possess emphasized acidic properties, and that the main reaction products with these catalysts are cyclohexene and cyclohexane.

Authors:
; ; ; ;
Publication Date:
OSTI Identifier:
6289933
Resource Type:
Journal Article
Journal Name:
J. Appl. Chem. USSR (Engl. Transl.); (United States)
Additional Journal Information:
Journal Volume: 61:4; Other Information: Translated from Zh. Prikl. Khim.; 61: No. 4, 811-815(Apr 1988)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ALUMINIUM OXIDES; CATALYTIC EFFECTS; CHROMIUM OXIDES; CYCLOHEXANOL; DEHYDRATION; MOLYBDENUM OXIDES; CATALYST SUPPORTS; CATALYSTS; CHEMICAL REACTION KINETICS; CHEMICAL REACTION YIELD; CHROMATOGRAPHY; CYCLOALKENES; CYCLOHEXANE; CYCLOHEXANONE; HETEROGENEOUS CATALYSIS; IMPREGNATION; KETONES; MATERIALS TESTING; PHENOLS; ALCOHOLS; ALKANES; ALKENES; ALUMINIUM COMPOUNDS; AROMATICS; CATALYSIS; CHALCOGENIDES; CHROMIUM COMPOUNDS; CYCLOALKANES; HYDROCARBONS; HYDROXY COMPOUNDS; KINETICS; MOLYBDENUM COMPOUNDS; ORGANIC COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; REACTION KINETICS; REFRACTORY METAL COMPOUNDS; SEPARATION PROCESSES; TESTING; TRANSITION ELEMENT COMPOUNDS; YIELDS; 400201* - Chemical & Physicochemical Properties

Citation Formats

Sibarov, D A, Dokuchaeva, T G, Lezdin, S U, Titova, A V, and Karpenko, E V. Dehydration of cyclohexanol on aluminum-chromium and aluminum-molybdenum catalysts. United States: N. p., 1988. Web.
Sibarov, D A, Dokuchaeva, T G, Lezdin, S U, Titova, A V, & Karpenko, E V. Dehydration of cyclohexanol on aluminum-chromium and aluminum-molybdenum catalysts. United States.
Sibarov, D A, Dokuchaeva, T G, Lezdin, S U, Titova, A V, and Karpenko, E V. 1988. "Dehydration of cyclohexanol on aluminum-chromium and aluminum-molybdenum catalysts". United States.
@article{osti_6289933,
title = {Dehydration of cyclohexanol on aluminum-chromium and aluminum-molybdenum catalysts},
author = {Sibarov, D A and Dokuchaeva, T G and Lezdin, S U and Titova, A V and Karpenko, E V},
abstractNote = {The purpose of this work was to investigate the activity of chromium and molybdenum oxides deposited on ..gamma..-Al/sub 2/O/sub 3/ in the conversion reaction of cyclohexanol. The authors established that chromium oxide deposited on aluminum oxide has a high activity in the dehydration reaction of cyclohexanol. The yield of ketone reached 95 mole %. They showed that Al-Mo catalysts possess emphasized acidic properties, and that the main reaction products with these catalysts are cyclohexene and cyclohexane.},
doi = {},
url = {https://www.osti.gov/biblio/6289933}, journal = {J. Appl. Chem. USSR (Engl. Transl.); (United States)},
number = ,
volume = 61:4,
place = {United States},
year = {Tue Sep 20 00:00:00 EDT 1988},
month = {Tue Sep 20 00:00:00 EDT 1988}
}