Excited states of homo- and heteronuclear-bridged bimetallic complexes of rhodium(I), iridium(I), platinum(II), and gold(I). Triplet manifold splittings, state assignments, and symmetry correlations
Journal Article
·
· Journal of Physical Chemistry
- Washington State Univ., Pullman, WA (United States)
Special information on bimetallic complexes of rhodium(I), iridium(I), platinum(II), and gold(I) is reported. We report spectra, polarization characteristics of the principal bands splittings of the triplet manifolds, and the response of the phosphorescence lifetimes to an external magnetic field. Our intent is to arrive at descriptions of the low-lying excited states that not only harmonize all the facts but also expose the reasons for the remarkable spectral similarities among species containing different metals and possessing diverse geometries. 26 refs., 6 figs., 5 tabs.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 62298
- Journal Information:
- Journal of Physical Chemistry, Vol. 99, Issue 20; Other Information: PBD: 18 May 1995
- Country of Publication:
- United States
- Language:
- English
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