Coordination conversion of cobalt(II) in binary aqueous-organic solvents (in Russian)
It has been shown that the thermochromic conversions of cobalt(II) in binary solvents are influenced by a number of factors: the nature of the solvent, the strength of the complexes of octahedral symmetry formed, the outer-sphere influence of the solvent on the complexes, the form of the anion, the solvation of the participants in the reaction, and the interaction of the components of the solvent with one another. A correlation between the strength and the spectral position of the absorption bands of the complexes of the activator has been established, and a spectroscopic criterion for selecting the solvents has been proposed. The expediency of using binary solvents to create effective thermochromic media with variable phototransmission has been substantiated.
- Research Organization:
- Leningrad Technological Institute of the Paper and Pulp Industry, USSR
- OSTI ID:
- 6225757
- Journal Information:
- Sov. J. Coordinat. Chem.; (United States), Vol. 11:1; Other Information: Translated from Koordinatsionnaya Khimiya; 11: No. 1, 53-60(Jan 1985)
- Country of Publication:
- United States
- Language:
- Russian
Similar Records
Pentavalent neptunyl ([OΞNpΞO]+) cation–cation interactions in aqueous/polar organic mixed-solvent media
Screening of metal complexes and organic solvents using the COSMOSAC-LANL model to enhance the energy density in a non-aqueous redox flow cell: an insight into the solubility
Related Subjects
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
COBALT COMPLEXES
PHOTOCHEMICAL REACTIONS
TEMPERATURE EFFECTS
COBALT COMPOUNDS
CATALYTIC EFFECTS
COMPLEXOMETRY
ORGANIC SOLVENTS
MATERIALS TESTING
ABSORPTION SPECTRA
ACETONE
AQUEOUS SOLUTIONS
BUTANOLS
COBALT BROMIDES
COBALT CHLORIDES
COBALT IODIDES
DMSO
ETHANOL
LIGHT TRANSMISSION
PENTANOLS
PHOTOCHROMIC MATERIALS
PROPANOLS
SOLVATION
WATER
ALCOHOLS
BROMIDES
BROMINE COMPOUNDS
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
DISPERSIONS
HALIDES
HALOGEN COMPOUNDS
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
IODIDES
IODINE COMPOUNDS
KETONES
MATERIALS
MIXTURES
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
OXYGEN COMPOUNDS
SOLUTIONS
SOLVENTS
SPECTRA
SULFOXIDES
TESTING
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
400201* - Chemical & Physicochemical Properties