Analytical use of copper(II)-neocuproine in the spectrophotometric determination of hydrazines
Journal Article
·
· Anal. Lett.; (United States)
This work characterizes a newly developed, sensitive and convenient spectrophotometric procedure for determination of sub-ppm concentrations of hydrazine and its organic derivatives. The method is based on formation of the cuprous neocuproine chelate after reaction of hydrazines with a prepared aqueous solution of the copper (II)--neocuproine complex. The cuprous chelate is then directly measured in aqueous solution at 458 nm. The effect of several experimental conditions influencing the reaction are presented and the method was employed for the analysis of 5 different hydrazine compounds. The standard deviation did not exceed /+/-/ 0.47%.
- Research Organization:
- National Research Centre, Cairo (Egypt)
- OSTI ID:
- 6190538
- Journal Information:
- Anal. Lett.; (United States), Vol. 21:10
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
HYDRAZINE
ABSORPTION SPECTROSCOPY
CHELATES
CHELATING AGENTS
COPPER COMPLEXES
EXPERIMENTAL DATA
PH VALUE
QUANTITATIVE CHEMICAL ANALYSIS
TRACE AMOUNTS
CHEMICAL ANALYSIS
COMPLEXES
DATA
INFORMATION
NITROGEN COMPOUNDS
NUMERICAL DATA
SPECTROSCOPY
TRANSITION ELEMENT COMPLEXES
400102* - Chemical & Spectral Procedures
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
HYDRAZINE
ABSORPTION SPECTROSCOPY
CHELATES
CHELATING AGENTS
COPPER COMPLEXES
EXPERIMENTAL DATA
PH VALUE
QUANTITATIVE CHEMICAL ANALYSIS
TRACE AMOUNTS
CHEMICAL ANALYSIS
COMPLEXES
DATA
INFORMATION
NITROGEN COMPOUNDS
NUMERICAL DATA
SPECTROSCOPY
TRANSITION ELEMENT COMPLEXES
400102* - Chemical & Spectral Procedures