skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Kinetics of hydrogenation of acetophenone to methylphenylcarbinol on KGA-43 copper-chromium catalyst

Abstract

The purpose of this investigation was to study the kinetics of the hydrogenation of acetophenone on KGA-43 catalyst, to establish a kinetic model for it, and to test the adequacy of the kinetic model for experiment. The kinetic studies of the hydrogenation of acetophenone on the new KGA-43 catalyst were conducted on a laboratory unit. Using the theory of steady-state reactions a kinetic model incorporating 10 unknown parameters was constructed. To determine the point estimates of the kinetic constants they used the method of maximum probability. The results of five repeated experiments were used to calculate the elements of a dispersion-covariation matrix of the reproducibility of the observations.

Authors:
; ; ; ; ;
Publication Date:
Research Org.:
D. I. Mendeleev Moscow Chemical-Engineering Institute (USSR)
OSTI Identifier:
6181080
Resource Type:
Journal Article
Journal Name:
J. Appl. Chem. USSR (Engl. Transl.); (United States)
Additional Journal Information:
Journal Volume: 61:3; Other Information: Translated from Zh. Prikl. Khim.; 61: No. 3, 565-571(Mar 1988)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ACETOPHENONE; HYDROGENATION; CHROMIUM ALLOYS; CATALYTIC EFFECTS; COPPER ALLOYS; ALCOHOLS; CATALYSTS; CHEMICAL REACTION KINETICS; HETEROGENEOUS CATALYSIS; KINETIC EQUATIONS; MATERIALS TESTING; MATHEMATICAL MODELS; MATRICES; PROBABILITY; STEADY-STATE CONDITIONS; ALLOYS; CATALYSIS; CHEMICAL REACTIONS; EQUATIONS; HYDROXY COMPOUNDS; KETONES; KINETICS; ORGANIC COMPOUNDS; REACTION KINETICS; TESTING; 400201* - Chemical & Physicochemical Properties

Citation Formats

Ziyatdinov, A Sh, Stepanenko, V V, Chernykh, I S, Leonova, E B, Pisarenko, V N, and Kafarov, V V. Kinetics of hydrogenation of acetophenone to methylphenylcarbinol on KGA-43 copper-chromium catalyst. United States: N. p., 1988. Web.
Ziyatdinov, A Sh, Stepanenko, V V, Chernykh, I S, Leonova, E B, Pisarenko, V N, & Kafarov, V V. Kinetics of hydrogenation of acetophenone to methylphenylcarbinol on KGA-43 copper-chromium catalyst. United States.
Ziyatdinov, A Sh, Stepanenko, V V, Chernykh, I S, Leonova, E B, Pisarenko, V N, and Kafarov, V V. 1988. "Kinetics of hydrogenation of acetophenone to methylphenylcarbinol on KGA-43 copper-chromium catalyst". United States.
@article{osti_6181080,
title = {Kinetics of hydrogenation of acetophenone to methylphenylcarbinol on KGA-43 copper-chromium catalyst},
author = {Ziyatdinov, A Sh and Stepanenko, V V and Chernykh, I S and Leonova, E B and Pisarenko, V N and Kafarov, V V},
abstractNote = {The purpose of this investigation was to study the kinetics of the hydrogenation of acetophenone on KGA-43 catalyst, to establish a kinetic model for it, and to test the adequacy of the kinetic model for experiment. The kinetic studies of the hydrogenation of acetophenone on the new KGA-43 catalyst were conducted on a laboratory unit. Using the theory of steady-state reactions a kinetic model incorporating 10 unknown parameters was constructed. To determine the point estimates of the kinetic constants they used the method of maximum probability. The results of five repeated experiments were used to calculate the elements of a dispersion-covariation matrix of the reproducibility of the observations.},
doi = {},
url = {https://www.osti.gov/biblio/6181080}, journal = {J. Appl. Chem. USSR (Engl. Transl.); (United States)},
number = ,
volume = 61:3,
place = {United States},
year = {Sat Aug 20 00:00:00 EDT 1988},
month = {Sat Aug 20 00:00:00 EDT 1988}
}