Hydrosilylation of unsaturated compounds in the presence of thiourea complexes of Pt(II) and Pd(II)

Journal Article · Tue May 10 00:00:00 EDT 1988 · J. Appl. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6180770

Brovko, V S; Vorb'ev-Desyatovskii, N V; Kukushkin, Yu N

Transition metal complexes, in particular H/sub 2/(PtCl/sub 6/), are effective catalysts in hydrosilylation reactions: the reaction of silanes and their substituted derivatives with olefins and acetylenes. The authors have shown that thiourea complexes of Pt(II) of the cationic type may catalyze hydrosilylation of 1-hexene and phenylacetylene by methyldichlorosilane. Terminal addition products are formed, and the reaction is characterized by 100% selectivity.

• Research Organization: Lensovet Leningrad Technological Institute (USSR)
• OSTI ID: 6180770
• Journal Information: J. Appl. Chem. USSR (Engl. Transl.); (United States), Vol. 60:11; Other Information: Translated from Zh. Prikl. Khim.; 60: No. 11, 2554-2556(Nov 1987)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
HEPTENES
CHEMICAL REACTIONS
PALLADIUM COMPLEXES
CATALYTIC EFFECTS
PLATINUM COMPLEXES
SILANES
THIOUREAS
TOLAN
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHROMATOGRAPHY
ORGANIC CHLORINE COMPOUNDS
ORGANIC ION EXCHANGERS
ORGANIC SILICON COMPOUNDS
REDUCTION
RESINS
ALKENES
AROMATICS
CARBONIC ACID DERIVATIVES
COMPLEXES
HYDRIDES
HYDROCARBONS
HYDROGEN COMPOUNDS
ION EXCHANGE MATERIALS
KINETICS
MATERIALS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC POLYMERS
ORGANIC SULFUR COMPOUNDS
PETROCHEMICALS
PETROLEUM PRODUCTS
POLYMERS
REACTION KINETICS
SEPARATION PROCESSES
SILICON COMPOUNDS
TRANSITION ELEMENT COMPLEXES
YIELDS
400201* - Chemical & Physicochemical Properties