Coordination compounds of manganese(II) with polyamines - catalysts of the oxidation of organic dyes by hydrogen peroxide

Journal Article · Sun Feb 01 00:00:00 EST 1987 · Sov. J. Coordinat. Chem.; (United States)

OSTI ID:6158903

Batyr, D G; Isak, V G; Kirienko, A A; Kharitonov, Yu Ya

The peroxidase activity of complexes of manganese(II) with polyamines has been characterized. A comparison of the original and literature data has led to the conclusion that the oxidation of organic substrates having some complexing ability with respect to Manganese(II) in Mn(II)-ligand-H/sub 2/O/sub 2/-S systems takes place according to an inner-sphere ion-molecule mechanism. In cases in which the substrate does not have any complexing ability with respect to Manganese(II), the oxidation process takes place according to an outer-sphere mechanism.

• Research Organization: V.I. Lenin Kishinev State Univ., USSR
• OSTI ID: 6158903
• Journal Information: Sov. J. Coordinat. Chem.; (United States), Vol. 12:4; Other Information: Translated from Koordinatsionnaya Khimiya; 12: No.4, 435-448(Apr 1986)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
DYES
HOMOGENEOUS CATALYSIS
OXIDATION
REDOX POTENTIAL
MANGANESE COMPLEXES
CATALYTIC EFFECTS
AMINES
CATALYSTS
CHEMICAL REACTION KINETICS
COMPLEXOMETRY
DISSOCIATION
ELECTRON SPIN RESONANCE
ELECTRON TRANSFER
GALLIUM COMPOUNDS
GLYCOLS
HETEROCYCLIC COMPOUNDS
HYDROGEN PEROXIDE
INDIGO
KINETIC EQUATIONS
MAGNESIUM COMPOUNDS
PEROXIDASES
POTASSIUM COMPOUNDS
PROPANOLS
SPECTROPHOTOMETRY
SUBSTRATES
SULFONATES
ALCOHOLS
ALKALI METAL COMPOUNDS
ALKALINE EARTH METAL COMPOUNDS
AROMATICS
AZAARENES
AZOLES
CATALYSIS
CHEMICAL REACTIONS
COMPLEXES
ENZYMES
EQUATIONS
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
INDOLES
KINETICS
MAGNETIC RESONANCE
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
OXIDOREDUCTASES
OXYGEN COMPOUNDS
PEROXIDES
PYRROLES
REACTION KINETICS
RESONANCE
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties