Reaction of alpha-gem-trichlorocarbonyl compounds with conjugated alkadienes

Journal Article · Thu Apr 10 00:00:00 EST 1986 · J. Org. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6136595

Startsev, V V; Zubritskii, L M; Gorbunkov, V D; Petrov, A A

Chloral and gem-trichloroacetone add to 1,3-alkadienes in the presence of copper(I) chloride with the formation of the corresponding ..gamma..,delta-unsaturated ..cap alpha..,..cap alpha..epsilon-trichlorocarbonyl compounds as mixtures of the E and Z isomers in a ratio in the order of 85:15. The reaction takes place under mild conditions and gives a high yield of the final products.

• Research Organization: Lensovet Leningrad Technological Institute, USSR
• OSTI ID: 6136595
• Journal Information: J. Org. Chem. USSR (Engl. Transl.); (United States), Vol. 21:11; Other Information: Translated from Zh. Org. Khim.; 21: No.11, 2292-2296(Nov 1985)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
74 ATOMIC AND MOLECULAR PHYSICS
ACETONE
ISOMERIZATION
COPPER CHLORIDES
CATALYTIC EFFECTS
DIENES
ISOMERS
CHEMICAL REACTION YIELD
NMR SPECTRA
ORGANIC CHLORINE COMPOUNDS
BINDING ENERGY
CHEMICAL BONDS
CHEMICAL SHIFT
COUPLING CONSTANTS
HYPERFINE STRUCTURE
INFRARED SPECTRA
J-J COUPLING
STEREOCHEMISTRY
VALENCE
VIBRATIONAL STATES
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COPPER COMPOUNDS
COPPER HALIDES
COUPLING
ENERGY
ENERGY LEVELS
EXCITED STATES
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
INTERMEDIATE COUPLING
KETONES
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
POLYENES
SPECTRA
TRANSITION ELEMENT COMPOUNDS
YIELDS
400201* - Chemical & Physicochemical Properties
640302 - Atomic
Molecular & Chemical Physics- Atomic & Molecular Properties & Theory