Kinetics of the reaction of diethylene glycol bis-chloroformate with allyl alcohol

Journal Article · Sat Oct 01 00:00:00 EDT 1988 · Kinet. Catal. (Engl. Transl.); (United States)

OSTI ID:6084714

Alekseev, N N; Shtoda, N F; Dzumedzei, N V

The kinetics of diethylene glycol bis-chloroformate solvolysis by excess allyl alcohol in toluene and carbon tetrachloride has been studied. Under conditions of a pseudofirst order reaction with respect to diethylene glycol bis-chloroformate the activation parameters confirm an addition-detachment mechanism.

• Research Organization: Ukrainian Scientific Research Institute for Plastics, Donetsk (USSR)
• OSTI ID: 6084714
• Journal Information: Kinet. Catal. (Engl. Transl.); (United States), Vol. 29:2; Other Information: Translated from Kinet. Katal.; 29: No. 2, 471-474(Mar-Apr 1988)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ALCOHOLS
ACTIVATION ENERGY
FORMATES
SOLVOLYSIS
GLYCOLS
CHEMICAL REACTION KINETICS
HYDROCHLORIC ACID
MATHEMATICAL MODELS
ORGANIC CHLORINE COMPOUNDS
POLYMERIZATION
POTASSIUM HYDROXIDES
POTENTIOMETRY
QUANTITY RATIO
SAPONIFICATION
TOLUENE
ALKALI METAL COMPOUNDS
ALKYLATED AROMATICS
AROMATICS
CARBOXYLIC ACID SALTS
CHEMICAL REACTIONS
DECOMPOSITION
ENERGY
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROLYSIS
HYDROXIDES
HYDROXY COMPOUNDS
INORGANIC ACIDS
KINETICS
LYSIS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
OXYGEN COMPOUNDS
POTASSIUM COMPOUNDS
REACTION KINETICS
TITRATION
400201* - Chemical & Physicochemical Properties