Reaction of SO2 with transition-metal hydrides. Synthesis and structure of ( -H)2Os3(CO)10( -SO2)

Jarvinen, G D; Ryan, R R

doi:10.1021/om00087a021

Title: Reaction of SO2 with transition-metal hydrides. Synthesis and structure of ( -H)2Os3(CO)10( -SO2)

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Abstract

The reaction of SO2 with the unsaturated cluster ( -H)2Os3(CO)10 yields the adduct ( -H)2Os3(CO)10( -SO2). The crystal structure of the adduct was determined and is reported. The molecular structure of the adduct was also determined and is closely related to that of the methylene complex.

Authors:: Jarvinen, G D; Ryan, R R

Publication Date:: Sun Jan 01 00:00:00 EST 1984

Research Org.:: Los Alamos National Lab., NM

OSTI Identifier:: 6052750

Resource Type:: Journal Article

Journal Name:: Organometallics; (United States)

Additional Journal Information:: Journal Volume: 3:9

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CARBONYLS; CHEMICAL PREPARATION; CRYSTAL STRUCTURE; MOLECULAR STRUCTURE; COMPLEXES; OSMIUM COMPOUNDS; SULFUR DIOXIDE; EXPERIMENTAL DATA; CHALCOGENIDES; DATA; INFORMATION; NUMERICAL DATA; OXIDES; OXYGEN COMPOUNDS; REFRACTORY METAL COMPOUNDS; SULFUR COMPOUNDS; SULFUR OXIDES; SYNTHESIS; TRANSITION ELEMENT COMPOUNDS; 400201* - Chemical & Physicochemical Properties; 400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)

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                    Jarvinen, G D, and Ryan, R R. Reaction of SO2 with transition-metal hydrides. Synthesis and structure of ( -H)2Os3(CO)10( -SO2).  United States: N. p., 1984. 
        Web.  doi:10.1021/om00087a021.

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                    Jarvinen, G D, & Ryan, R R. Reaction of SO2 with transition-metal hydrides. Synthesis and structure of ( -H)2Os3(CO)10( -SO2).  United States.  https://doi.org/10.1021/om00087a021

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                    Jarvinen, G D, and Ryan, R R. 1984.  
        "Reaction of SO2 with transition-metal hydrides. Synthesis and structure of ( -H)2Os3(CO)10( -SO2)".  United States.  https://doi.org/10.1021/om00087a021.

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@article{osti_6052750,

  title        = {Reaction of SO2 with transition-metal hydrides. Synthesis and structure of ( -H)2Os3(CO)10( -SO2)},

  author       = {Jarvinen, G D and Ryan, R R},

  abstractNote = {The reaction of SO2 with the unsaturated cluster ( -H)2Os3(CO)10 yields the adduct ( -H)2Os3(CO)10( -SO2). The crystal structure of the adduct was determined and is reported. The molecular structure of the adduct was also determined and is closely related to that of the methylene complex.},

  doi          = {10.1021/om00087a021},

  url          = {https://www.osti.gov/biblio/6052750},
  journal      = {Organometallics; (United States)},
number       = ,

  volume       = 3:9,

  place        = {United States},

  year         = {Sun Jan 01 00:00:00 EST 1984},

  month        = {Sun Jan 01 00:00:00 EST 1984}

}

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