Mass-spectrometric investigation of ortho-hydroxynitrosoarenes and their rearrangement products - /beta/(2-cyanoaryl)acrylic acids

Journal Article · Mon Jun 20 00:00:00 EDT 1988 · J. Org. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6008085

Terent'ev, P B; Rakhimi, M I; Stankevichus, A P; Kalandarishvili, A G; Bundel', Yu G

Comparative analysis of the mass spectra of 2-hydroxy-1-nitrosonaphthalene, its benzo-substituted derivatives, 2-hydroxy-1-nitrosoanthracene, 2-hydroxy-1-nitrosophenanthrene, and also the products from their Beckmann rearrangement of the second kind, i.e., ortho-cyanocinnamic (benzocinnamic) acids, shows that the molecular ions of the ortho-nitrosohydroxyarenes formed under electron impact largely retain the topology of the initial molecule and do not undergo a Beckmann rearrangement of the second kind to an appreciable degree.

• Research Organization: M.V. Lomonosov Moscow State Univ. (USSR)
• OSTI ID: 6008085
• Journal Information: J. Org. Chem. USSR (Engl. Transl.); (United States), Vol. 24:1; Other Information: Translated from Zh. Org. Khim.; 24: No. 1, 163-167 (Jan 1988)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
74 ATOMIC AND MOLECULAR PHYSICS
ACRYLIC ACID ESTERS
MASS SPECTRA
AROMATICS
HYDROXY COMPOUNDS
MOLECULAR IONS
DISSOCIATION
NITROSO COMPOUNDS
POLYATOMIC MOLECULES
ELECTRON-MOLECULE COLLISIONS
BROMINE 79
CINNAMIC ACID
ELECTRON BEAMS
IONIZATION
ISOMERIZATION
METASTABLE STATES
MOLECULAR STRUCTURE
VALENCE
BEAMS
BROMINE ISOTOPES
CARBOXYLIC ACID ESTERS
CARBOXYLIC ACIDS
CHARGED PARTICLES
CHEMICAL REACTIONS
COLLISIONS
ELECTRON COLLISIONS
ENERGY LEVELS
ESTERS
EXCITED STATES
INTERMEDIATE MASS NUCLEI
IONS
ISOTOPES
LEPTON BEAMS
MOLECULE COLLISIONS
MOLECULES
MONOCARBOXYLIC ACIDS
NUCLEI
ODD-EVEN NUCLEI
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PARTICLE BEAMS
RADIOISOTOPES
SECONDS LIVING RADIOISOTOPES
SPECTRA
STABLE ISOTOPES
400201* - Chemical & Physicochemical Properties
640304 - Atomic
Molecular & Chemical Physics- Collision Phenomena