Dipole moments and structure of some (1-adamantyl)germanes

Journal Article · Sun Jan 10 00:00:00 EST 1988 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6007465

Kartsev, G N; Akin'shina, G A; Gar, T K; Chernysheva, O N

The dipole moments of ten derivatives of (1-adamantyl)germane (I)-(X) of general formula 1-AdGeR/sub 3//sup i/, in which R/sub 3//sup i/=H/sub 3/ (I), Me/sub 3/ (II), Cl/sub 3/ (III), Br/sub 3/ (IV), I/sub 3/ (V), Me/sub 2/H (VI), Me/sub 2/Cl (VII), (OMe)/sub 3/ (VIII), (OEt)/sub 3/ (IX), (OCHME/sub 2/)/sub 3/ (X), and four tert-butyl derivatives of germanium t-BuGeR/sub 3/ were studied, in which R = Me (XI), Cl (XII), Br(XIII), I (XIV). As a result of the investigation of the ten derivatives, the enhanced polarity of these compounds relative to the usual alkylgermanes was show, which was associated with both the peculiarities of the structure of the adamantane skeleton, and with the high mobility of electron density in the GeX/sub 3/ group. The adamantyl substitutent showed acceptor properties.

• Research Organization: M.V. Lomonosov Moscow Institute of Fine Chemical Technology (USSR)
• OSTI ID: 6007465
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Vol. 57:7; Other Information: Translated from Zh. Obshch. Khim.; 57: No. 7, 1576-1580(Jul 1987)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CYCLOALKANES
ELECTRIC DIPOLE MOMENTS
GERMANIUM COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
ADAMANTANE
BINDING ENERGY
ELECTRON DENSITY
ELECTRON MOBILITY
GERMANIUM BROMIDES
GERMANIUM CHLORIDES
GERMANIUM HYDRIDES
GERMANIUM IODIDES
POLARIZATION
VALENCE
ALKANES
BROMIDES
BROMINE COMPOUNDS
CHLORIDES
CHLORINE COMPOUNDS
DIPOLE MOMENTS
ELECTRIC MOMENTS
ENERGY
HALIDES
HALOGEN COMPOUNDS
HYDRIDES
HYDROCARBONS
HYDROGEN COMPOUNDS
IODIDES
IODINE COMPOUNDS
MOBILITY
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
PARTICLE MOBILITY
400201* - Chemical & Physicochemical Properties