Stereochemistry of the epoxidation of internal perfluoroalkenes with sodium hypochlorite
Journal Article
·
· J. Org. Chem. USSR (Engl. Transl.); (United States)
OSTI ID:5971341
The authors studied the epoxidation of the mixture of cis and trans isomers of internal disubstituted perfluoroalkenes with sodium hypochlorite. Epoxidation was realized with an alkaline aqueous solution of sodium hypochlorite in the presence of acetonitrile. The epoxidation of the geometric isomers of internal disubstituted perfluoroalkenes by sodium hypochlorite is stereospecific. The /sup 19/F NMR spectra of the cis and trans isomers of internal perfluoroolefin oxides were obtained, and the relationships are discussed.
- Research Organization:
- Institute of Chemistry, Sverdlovsk (USSR)
- OSTI ID:
- 5971341
- Journal Information:
- J. Org. Chem. USSR (Engl. Transl.); (United States), Vol. 24:2; Other Information: Translated from Zh. Org. Khim.; 24: No. 2, 371-377 (Feb 1988)
- Country of Publication:
- United States
- Language:
- English
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OSTI ID:5971341
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OSTI ID:5971341
Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ALKANES
STEREOCHEMISTRY
EPOXIDES
NMR SPECTRA
FLUORINATED ALIPHATIC HYDROCARBONS
OXYCHLORIDES
CATALYTIC EFFECTS
SODIUM COMPOUNDS
CHEMICAL REACTION YIELD
COUPLING CONSTANTS
DOUBLE RESONANCE METHODS
FLUORINE 19
ISOMERIZATION
ISOMERS
J-J COUPLING
STRUCTURAL CHEMICAL ANALYSIS
ALKALI METAL COMPOUNDS
CHEMICAL REACTIONS
CHLORINE COMPOUNDS
COUPLING
FLUORINE ISOTOPES
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROCARBONS
INTERMEDIATE COUPLING
ISOTOPES
LIGHT NUCLEI
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXYGEN COMPOUNDS
SPECTRA
STABLE ISOTOPES
YIELDS
400201* - Chemical & Physicochemical Properties
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ALKANES
STEREOCHEMISTRY
EPOXIDES
NMR SPECTRA
FLUORINATED ALIPHATIC HYDROCARBONS
OXYCHLORIDES
CATALYTIC EFFECTS
SODIUM COMPOUNDS
CHEMICAL REACTION YIELD
COUPLING CONSTANTS
DOUBLE RESONANCE METHODS
FLUORINE 19
ISOMERIZATION
ISOMERS
J-J COUPLING
STRUCTURAL CHEMICAL ANALYSIS
ALKALI METAL COMPOUNDS
CHEMICAL REACTIONS
CHLORINE COMPOUNDS
COUPLING
FLUORINE ISOTOPES
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROCARBONS
INTERMEDIATE COUPLING
ISOTOPES
LIGHT NUCLEI
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXYGEN COMPOUNDS
SPECTRA
STABLE ISOTOPES
YIELDS
400201* - Chemical & Physicochemical Properties