Heteroorganic furan derivatives. 61. Trimethyl (5-methyl-2-furyl) silane and trimethyl (5-methyl-2-furyl) german

Journal Article · Wed Jul 01 00:00:00 EDT 1987 · Chem. Heterocycl. Compd. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00475465· OSTI ID:5926219

Lukevits, E; Ignatovich, L M; Iovel', I G; Gol'dberg, Yu Sh; Shimanskaya, M V

The transformations of trimethyl (5-methyl-2-furyl)silane and trimethyl (5-methyl-2-furyl) germane were studied upon vapor-phase oxidation by atmospheric oxygen on a V-Mo-Ag-O catalyst. Under these conditions, trimethyl(5-formyl-2-furyl)-silane and trimethyl (5-formyl-2-furyl) germane are formed albeit in only 5-7% yield. This low yield is a consequence of the thermal instability of the starting compounds and the aldehydes formed. The oxidation of 2-methyl-5-tert-butylfuran was studied under comparable conditions. The corresponding aldehyde was obtained in 30% yield. A scheme was proposed for the catalytic oxidation of 5-substituted 2-methylfurans.

• Research Organization: Institute of Organic Synthesis, Riga, USSR
• OSTI ID: 5926219
• Journal Information: Chem. Heterocycl. Compd. (Engl. Transl.); (United States), Vol. 23:1; Other Information: Translated from Khim. Geterotsikl. Soedin.; 23: No. 1, 22-24(Jan 1987)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ALDEHYDES
SYNTHESIS
FURANS
OXIDATION
GERMANIUM COMPLEXES
MOLYBDENUM OXIDES
CATALYTIC EFFECTS
SILICON COMPLEXES
SILVER OXIDES
VANADIUM OXIDES
CHEMICAL REACTION YIELD
CHROMATOGRAPHY
MASS SPECTRA
CHALCOGENIDES
CHEMICAL REACTIONS
COMPLEXES
HETEROCYCLIC COMPOUNDS
MOLYBDENUM COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
REFRACTORY METAL COMPOUNDS
SEPARATION PROCESSES
SILVER COMPOUNDS
SPECTRA
TRANSITION ELEMENT COMPOUNDS
VANADIUM COMPOUNDS
YIELDS
400201* - Chemical & Physicochemical Properties