Solid phase catalysts and reagents. Final technical report, July 1, 1977-December 31, 1983

Technical Report · Thu Dec 01 00:00:00 EST 1983

OSTI ID:5912009

Regen, S L

Research supported under this grant for the period 1/1/80-12/31/83 has involved six major areas: (1) defining polymer structure-activity relationships in triphase catalytic systems, (2) developing polyether- and polyamide-based catalysts for practical organic synthesis, (3) establishing new synthetic entries into macrolides based on triphase and phase-transfer catalytic principles, (4) introducing new polymeric and monomeric mercury reagents for use in organic synthesis, (5) clarifying and quantifying kinetic isolation within cross-linked polystyrene, and (6) elucidating the kinetic and mechanistic features of the hydrolysis of organic halides in aqueous - liquid organic two phase systems. Detailed reports are presented for the six areas. For the period 7/1/77-12/31/79 brief summaries are presented for the following areas: (1) insolubilized hexamethylphosphoramide as a solid solvent; (2) triphase catalysis, consideration of catalyst and experimental conditions for simple nucleophilic displacement; (3) selectivity features of polystrene-based triphase catalysts; (4) evidence for an S/sub N//sup 1/ reaction occurring at a toluene-water interface; (5) solid phase cosolvents - triphase catalytic hydrolysis of 1-bromoadamantane; (6) consideration of the role of stirring and catalyst efficiency of polystyrene-based triphase catalysts. 24 references.

• Research Organization: Marquette Univ., Milwaukee, WI (USA)
• DOE Contract Number: AC02-77ER04446
• OSTI ID: 5912009
• Report Number(s): DOE/ER/04446-5; COO-4446-5; ON: DE85009317; TRN: 85-007793
• Resource Relation: Other Information: Portions of this document are illegible in microfiche products
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ALKYLATION
CATALYSTS
CHEMICAL PREPARATION
RESEARCH PROGRAMS
DEHALOGENATION
DEHYDROGENATION
HYDROLYSIS
CATALYSIS
CATALYTIC EFFECTS
CROSS-LINKING
POLYAMIDES
POLYETHYLENE GLYCOLS
POLYMERS
POLYSTYRENE
QUATERNARY COMPOUNDS
REAGENTS
RESINS
ALCOHOLS
AMINES
AMMONIUM COMPOUNDS
CHEMICAL REACTIONS
DECOMPOSITION
GLYCOLS
HYDROXY COMPOUNDS
LYSIS
MATERIALS
ORGANIC COMPOUNDS
ORGANIC POLYMERS
PETROCHEMICALS
PETROLEUM PRODUCTS
PLASTICS
POLYMERIZATION
POLYOLEFINS
POLYVINYLS
SOLVOLYSIS
SYNTHESIS
SYNTHETIC MATERIALS
400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)