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Title: Explosion hazards of oil shale dusts: Limits, pressures, and ignitability

Conference · · Oil Shale Symp. Proc.; (United States)
OSTI ID:5905320

The Bureau of Mines, under a cooperative agreement with the Colorado Mining Association, has investigated the explosion hazards of fine oil shale dust. Six grades of dust of varying oil assay (from 20 to 55 gal/ton) but with similar size distributions were studied in a 20-L explosibility chamber and in a 1.2-L ignitability furnace. Lean limits of flammability, maximum explosion pressures, and maximum rates of pressure rise were measured in the 20-L chamber and thermal autoignition temperatures were measured in the 1.2-L furnace. Electrical spark ignition measurements were made in both systems. For comparison with the oil shales, Pittsburgh seam bituminous coal, gilsonite, sulfide ore, and anthracite coal were also tested. The lean limits of flammability vary inversely with oil assay and all grades of shale dust with oil assays of 20 to 24 gal/ton or greater are capable of generating dust explosions at concentrations above their respective lean limits. Even the 50 gal/ton shale dust is less flammable than Pittsburgh bituminous coal. In terms of electrical ignitability, the shales are at least an order of magnitude less ignitable than the coal. The shale dust clouds are, however, somewhat more easily ignited thermally than the coal. Microscopic observations of the various grades of dust were made in order to determine whether the particle size variable could be isolated and studied independently of kerogen content of the shale dust. The implications of preliminary data, which suggest that those two variables are not readily separable, are also considered.

Research Organization:
U.S. Department of the Interior, Bureau of Mines, Pittsburgh Research Center, Pittsburgh, PA
OSTI ID:
5905320
Report Number(s):
CONF-8404121-
Journal Information:
Oil Shale Symp. Proc.; (United States), Conference: 17. oil shale symposium, Golden, CO, USA, 16 Apr 1984
Country of Publication:
United States
Language:
English