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Title: Reaction of /alpha/,/beta/-unsaturated acyl isothiocyanates with salts of dithiocarbamic acids

Abstract

The reaction of unsaturated isothiocyanates with the sodium and calcium salts of N-alkyl- and N,N-dialkyldithiocarbamic acids was studied. Depending on the structure of the dithiocarbamate, the reaction products are thiazines or acyl dithiocarbamates. For the salts of methyldithiocarbamic acid the effect of the concentration and the nature of the metal on the relative yields of 6-phenyl-3-methylpropiorhodanine and 6-phenylpropiorhodanine was studied. A method is proposed for the synthesis of 3-substituted propiorhodanines.

Authors:
; ;
Publication Date:
Research Org.:
M.V. Lomonosov Moscow State Univ. (USSR)
OSTI Identifier:
5887929
Resource Type:
Journal Article
Journal Name:
J. Org. Chem. USSR (Engl. Transl.); (United States)
Additional Journal Information:
Journal Volume: 24:8; Other Information: Translated from Zh. Org. Khim.; 24: No. 8, 1576-1581 (Aug 1988)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CALCIUM COMPOUNDS; CATALYTIC EFFECTS; CARBAMATES; CHEMICAL REACTION KINETICS; ISOTHIOCYANATES; SODIUM COMPOUNDS; ACYLATION; AMIDES; AZINES; CHEMICAL REACTION YIELD; DEHYDROCYCLIZATION; HYDROLYSIS; INFRARED SPECTRA; MASS SPECTRA; NMR SPECTRA; RADICALS; STRUCTURAL CHEMICAL ANALYSIS; ALKALI METAL COMPOUNDS; ALKALINE EARTH METAL COMPOUNDS; CARBONIC ACID DERIVATIVES; CARBOXYLIC ACID SALTS; CHEMICAL REACTIONS; DECOMPOSITION; HETEROCYCLIC COMPOUNDS; KINETICS; LYSIS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC SULFUR COMPOUNDS; REACTION KINETICS; SOLVOLYSIS; SPECTRA; YIELDS; 400201* - Chemical & Physicochemical Properties

Citation Formats

Krus, K, Masias, A, and Beletskaya, I P. Reaction of /alpha/,/beta/-unsaturated acyl isothiocyanates with salts of dithiocarbamic acids. United States: N. p., 1989. Web.
Krus, K, Masias, A, & Beletskaya, I P. Reaction of /alpha/,/beta/-unsaturated acyl isothiocyanates with salts of dithiocarbamic acids. United States.
Krus, K, Masias, A, and Beletskaya, I P. 1989. "Reaction of /alpha/,/beta/-unsaturated acyl isothiocyanates with salts of dithiocarbamic acids". United States.
@article{osti_5887929,
title = {Reaction of /alpha/,/beta/-unsaturated acyl isothiocyanates with salts of dithiocarbamic acids},
author = {Krus, K and Masias, A and Beletskaya, I P},
abstractNote = {The reaction of unsaturated isothiocyanates with the sodium and calcium salts of N-alkyl- and N,N-dialkyldithiocarbamic acids was studied. Depending on the structure of the dithiocarbamate, the reaction products are thiazines or acyl dithiocarbamates. For the salts of methyldithiocarbamic acid the effect of the concentration and the nature of the metal on the relative yields of 6-phenyl-3-methylpropiorhodanine and 6-phenylpropiorhodanine was studied. A method is proposed for the synthesis of 3-substituted propiorhodanines.},
doi = {},
url = {https://www.osti.gov/biblio/5887929}, journal = {J. Org. Chem. USSR (Engl. Transl.); (United States)},
number = ,
volume = 24:8,
place = {United States},
year = {Tue Jan 10 00:00:00 EST 1989},
month = {Tue Jan 10 00:00:00 EST 1989}
}