Kinetic relationships governing addition of methanol to methyl acrylate

Journal Article · Thu Nov 10 00:00:00 EST 1988 · J. Org. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5887756

Chubarov, G A; Danov, S M; Kutnyaya, M Yu

The kinetic relationships governing the addition of methanol to methyl acrylate and the reverse reaction, i.e., the elimination of methanol from methyl /beta/-methoxypropionate catalyzed by sulfuric and p-toluenesulfonic acids, were investigated. The rate of the forward reaction depends on the concentrations of methyl acrylate, methanol, and the catalyst, and the rate of the reverse reaction depends on the concentration of methyl /beta/-methoxypropionate and of the catalyst. A kinetic expression which describes the process well was obtained.

• Research Organization: A.A. Zhdanov Gor'skii Polytechnical Institute (USSR)
• OSTI ID: 5887756
• Journal Information: J. Org. Chem. USSR (Engl. Transl.); (United States), Vol. 24:6; Other Information: Translated from Zh. Org. Khim.; 24: No. 6, 1141-1144 (Jun 1988)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ACRYLIC ACID ESTERS
CATALYSIS
METHANOL
SULFONIC ACID ESTERS
CATALYTIC EFFECTS
SULFURIC ACID
ACRYLIC ACID
ARRHENIUS EQUATION
CATALYSTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHROMATOGRAPHY
DOUBLE BONDS
ESTERIFICATION
KINETIC EQUATIONS
MATHEMATICAL MODELS
QUANTITY RATIO
ALCOHOLS
CARBOXYLIC ACID ESTERS
CARBOXYLIC ACIDS
CHEMICAL BONDS
CHEMICAL REACTIONS
EQUATIONS
ESTERS
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
INORGANIC ACIDS
KINETICS
MONOCARBOXYLIC ACIDS
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
REACTION KINETICS
SEPARATION PROCESSES
YIELDS
400201* - Chemical & Physicochemical Properties