Mechanism of methanol conversion over zeolite
Abstract
Details of the reaction mechanisms of conversions of methanol to various alkanes and alkenes were investigated. A discussion of the autocatalytic phenomena of the conversion of methanol over ZSM-5 zeolite was included. The temperature dependence and acidity aspects of the reaction rate were discussed. Also the use of Nafion-H and heteropolyacids as catalysts of conversion was also included. A detailed description of the self-condensation of methyl iodine over Ag/sub 3/PW/sub 12/O/sub 40/ was given. The distribution of hydrocarbon products on the reaction at various temperatures, reaction times, and molar ratios of reactants was given in tabular form.
- Authors:
- Publication Date:
- Research Org.:
- Tokyo Inst. of Tech., Japan
- OSTI Identifier:
- 5841473
- Report Number(s):
- CONF-830303-
Journal ID: CODEN: ACFPA
- Resource Type:
- Conference
- Journal Name:
- Prepr. Pap. - Am. Chem. Soc., Div. Fuel Chem.; (United States)
- Additional Journal Information:
- Journal Volume: 28:2; Conference: 185. American Chemical Society national meeting, Seattle, WA, USA, 20 Mar 1983
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 02 PETROLEUM; 10 SYNTHETIC FUELS; METHANOL; CHEMICAL REACTIONS; ZEOLITES; CATALYTIC EFFECTS; ALKANES; ALKENES; IODINE COMPOUNDS; PH VALUE; REACTION KINETICS; SILVER COMPOUNDS; TEMPERATURE DEPENDENCE; TUNGSTEN COMPOUNDS; ALCOHOLS; HALOGEN COMPOUNDS; HYDROCARBONS; HYDROXY COMPOUNDS; INORGANIC ION EXCHANGERS; ION EXCHANGE MATERIALS; KINETICS; MATERIALS; MINERALS; ORGANIC COMPOUNDS; TRANSITION ELEMENT COMPOUNDS; 020500* - Petroleum- Products & By-Products; 090121 - Hydrocarbon Fuels- Chemical Synthesis- (1976-1989)
Citation Formats
Ono, Y. Mechanism of methanol conversion over zeolite. United States: N. p., 1983.
Web.
Ono, Y. Mechanism of methanol conversion over zeolite. United States.
Ono, Y. 1983.
"Mechanism of methanol conversion over zeolite". United States.
@article{osti_5841473,
title = {Mechanism of methanol conversion over zeolite},
author = {Ono, Y},
abstractNote = {Details of the reaction mechanisms of conversions of methanol to various alkanes and alkenes were investigated. A discussion of the autocatalytic phenomena of the conversion of methanol over ZSM-5 zeolite was included. The temperature dependence and acidity aspects of the reaction rate were discussed. Also the use of Nafion-H and heteropolyacids as catalysts of conversion was also included. A detailed description of the self-condensation of methyl iodine over Ag/sub 3/PW/sub 12/O/sub 40/ was given. The distribution of hydrocarbon products on the reaction at various temperatures, reaction times, and molar ratios of reactants was given in tabular form.},
doi = {},
url = {https://www.osti.gov/biblio/5841473},
journal = {Prepr. Pap. - Am. Chem. Soc., Div. Fuel Chem.; (United States)},
number = ,
volume = 28:2,
place = {United States},
year = {Sat Jan 01 00:00:00 EST 1983},
month = {Sat Jan 01 00:00:00 EST 1983}
}
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