Photophysics of poly(ethylene terephthalate): Ultraviolet absorption and emission
Journal Article
·
· Journal of Physical Chemistry; (USA)
- Pacific Northwest Lab., Richland, WA (USA)
- IBM Thomas J. Watson Research Center, Yorktown Heights, NY (USA)
Polarized and unpolarized emission spectra for poly(ethylene terephthalate) are presented, and a new phosphorescence peak at 564 nm is reported. The spectroscopically parameterized CNDO/S3 model is used to provide a detailed description of the absorption and monomeric emission. Moreover, preliminary computations on an idealized terephthalate dimer indicate that the 368-nm fluorescence and the newly reported phosphorescence emission may be attributable to an associated ground-state dimer.
- OSTI ID:
- 5775763
- Journal Information:
- Journal of Physical Chemistry; (USA), Vol. 95:2; ISSN 0022-3654
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
PHTHALATES
ABSORPTION SPECTRA
EMISSION SPECTRA
EXPERIMENTAL DATA
MEASURING METHODS
ORGANIC POLYMERS
PHOSPHORESCENCE
CARBOXYLIC ACID SALTS
DATA
INFORMATION
LUMINESCENCE
NUMERICAL DATA
ORGANIC COMPOUNDS
POLYMERS
SPECTRA
400102* - Chemical & Spectral Procedures
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
PHTHALATES
ABSORPTION SPECTRA
EMISSION SPECTRA
EXPERIMENTAL DATA
MEASURING METHODS
ORGANIC POLYMERS
PHOSPHORESCENCE
CARBOXYLIC ACID SALTS
DATA
INFORMATION
LUMINESCENCE
NUMERICAL DATA
ORGANIC COMPOUNDS
POLYMERS
SPECTRA
400102* - Chemical & Spectral Procedures