Ritter reaction of 2-methyladamanthan-2-ol

Journal Article · Fri Jul 10 00:00:00 EDT 1987 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5775007

Kozlov, N G; Popova, L A; Knizhnikov, V A; Ol'dekop, Yu A

The reaction between 2-methyladamantan-2-ol and various nitriles in the presence of concentrated sulfuric acid leads to the stereoselective formation of the corresponding N-substituted-2-methyladamantyl-2-amides. Only when the reaction is carried out with chloroacetonitrile is homoadamantyl-2-chloracetamide obtained in addition to 2-methyladamantyl-2-chloroacetamide. Hydrogen 1 and carbon 13 NMR spectra were obtained in deuterated chloroform. Mass spectra was obtained with an ionizing electron energy of 70 eV. A full spectral analysis was performed.

• Research Organization: Institute of Physical Organic Chemistry, Minsk, USSR
• OSTI ID: 5775007
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Vol. 57:1; Other Information: Translated from Zh. Obshch. Khim.; 57: No. 1, 171-174(Jan 1987)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
74 ATOMIC AND MOLECULAR PHYSICS
ALCOHOLS
ISOMERIZATION
MASS SPECTRA
NMR SPECTRA
AMIDES
SYNTHESIS
NITRILES
ADAMANTANE
CARBON 13
CATALYTIC EFFECTS
CHEMICAL SHIFT
CHLOROFORM
COMPARATIVE EVALUATIONS
COUPLING CONSTANTS
DEUTERIUM COMPOUNDS
ELECTRON-ION COLLISIONS
HYDROGEN 1
IONIZATION
J-J COUPLING
ORGANIC CHLORINE COMPOUNDS
SULFURIC ACID
ALKANES
CARBON ISOTOPES
CHEMICAL REACTIONS
CHLORINATED ALIPHATIC HYDROCARBONS
COLLISIONS
COUPLING
CYCLOALKANES
ELECTRON COLLISIONS
EVEN-ODD NUCLEI
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
HYDROXY COMPOUNDS
INORGANIC ACIDS
INTERMEDIATE COUPLING
ION COLLISIONS
ISOTOPES
LIGHT NUCLEI
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
SPECTRA
STABLE ISOTOPES
400201* - Chemical & Physicochemical Properties
640302 - Atomic
Molecular & Chemical Physics- Atomic & Molecular Properties & Theory