Shape resonant features in the photoionization spectra of NO

Journal Article · Fri Jan 01 00:00:00 EST 1982 · Journal of Chemical Physics

DOI:https://doi.org/10.1063/1.443138· OSTI ID:5756259

Wallace, Scott ^[1]; Dill, Dan ^[2]; Dehmer, Joseph L. ^[3]

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1. MIT (Massachusetts Inst. of Technology), Cambridge, MA (United States)
2. Boston Univ., MA (United States). Dept. of Chemistry
3. Argonne National Lab. (ANL), Argonne, IL (United States)

Calculations of core and valence level photoionization spectra of NO are presented and compared with available experimental data. A low-lying continuum shape resonance is identified in the sigma photoionization channel, which is the analog of similar states found in other first-row diatomic molecules. Both partial cross sections and photoelectron angular distributions are discussed, and the effect of nuclear motion on these observables is treated.

• Research Organization: MIT (Massachusetts Inst. of Technology), Cambridge, MA (United States)
• Sponsoring Organization: National Science Foundation (NSF); USDOE
• DOE Contract Number: CHE78-08707
• OSTI ID: 5756259
• Journal Information: Journal of Chemical Physics, Vol. 76, Issue 3; ISSN 0021-9606: JCPSA6
• Publisher: American Institute of Physics (AIP)
• Country of Publication: United States
• Language: English

Related Subjects

74 ATOMIC AND MOLECULAR PHYSICS
NITRIC OXIDE
PHOTOELECTRON SPECTROSCOPY
PHOTOIONIZATION
ANGULAR DISTRIBUTION
CROSS SECTIONS
CHALCOGENIDES
DISTRIBUTION
ELECTRON SPECTROSCOPY
IONIZATION
NITROGEN COMPOUNDS
NITROGEN OXIDES
OXIDES
OXYGEN COMPOUNDS
SPECTROSCOPY
640302* - Atomic
Molecular & Chemical Physics- Atomic & Molecular Properties & Theory