Primary and diagenetic carbonates in the anoxic sediments of Lake Bosumtwi, Ghana
Cores of organic-rich muds from the tropical meteorite crater Lake Bosumtwi, Ghana, contain laminae of authigenic calcite polyhedra and aragonite needles, as well as scattered diagenetic calcite, Mg-calcite spherulites, and aggregates of dolomite crystals. Their respective origins are traced by analyses of oxygen and carbon stable isotopes. Anoxic dolomite and Mg-calcite formed in pore waters reflecting highest degrees of evaporative concentration and high rates of methanogenesis. Carbon dioxide reduction must have been the dominant methanogenic pathway, producing diagenetic carbonates with ..delta../sup 13/C values up to + 27% PDB. This example shows the inherent problems of interpreting bulk samples with progressive mineralogical sequences of calcite to Mg-calcite to aragonite to dolomite merely in terms of Mg/sup 2 +//Ca/sup 2 +/ in lake waters. It provides a model for the interpretation of ancient lacustrine carbonates from organic-rich environments.
- Research Organization:
- Universitetet i Bergen, Norway
- OSTI ID:
- 5754825
- Journal Information:
- Geology; (United States), Vol. 14:11
- Country of Publication:
- United States
- Language:
- English
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GEOLOGIC DEPOSITS
DIAGENESIS
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NATURAL GAS DEPOSITS
GEOLOGIC MODELS
CALCITE
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CARBONATE ROCKS
DOLOMITE
LAKES
METHANE
ORGANIC MATTER
REDUCTION
SEDIMENTS
SYNTHESIS
AFRICA
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ALKANES
CALCIUM CARBONATES
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CARBON OXIDES
CARBONATE MINERALS
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DEVELOPING COUNTRIES
HYDROCARBONS
MAGNESIUM CARBONATES
MAGNESIUM COMPOUNDS
MINERAL RESOURCES
MINERALS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
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SEDIMENTARY ROCKS
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