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Title: (Chemical probes of charge transfer at semiconductor/liquid junctions). Technical report for May 15, 1984-January 15, 1985

Abstract

A study of the effects of surface energetics and surface oxide layers on the cyclic voltametry of metallocenes at nonilluminated p- and n-InP electrodes has been completed. Nearly ideal semiconductor/solution interfaces can be prepared, it was concluded, and the voltammetry of metallocenes is a way to probe electron transfer across this interface under different surface energetic conditions. Single crystals of WSe/sub 2/ were grown by chemical vapor transport. A computer program was written to collect voltametric data and calculated convoluted currents, and it is used to examine the kinetics of charge transfer across the semiconductor solution interface. (LEW)

Authors:
Publication Date:
Research Org.:
Colorado Univ., Boulder (USA)
OSTI Identifier:
5738618
Report Number(s):
DOE/ER/13247-1
ON: DE85013082
DOE Contract Number:  
FG02-84ER13247
Resource Type:
Technical Report
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CHARGE TRANSPORT; PROBES; ELECTROCHEMICAL CELLS; CAPACITANCE; CHEMICAL VAPOR DEPOSITION; DATA ACQUISITION; INDIUM PHOSPHIDES; OXIDES; TUNGSTEN SELENIDES; VOLTAMETRY; CHALCOGENIDES; CHEMICAL COATING; DEPOSITION; ELECTRICAL PROPERTIES; INDIUM COMPOUNDS; OXYGEN COMPOUNDS; PHOSPHIDES; PHOSPHORUS COMPOUNDS; PHYSICAL PROPERTIES; PNICTIDES; REFRACTORY METAL COMPOUNDS; SELENIDES; SELENIUM COMPOUNDS; SURFACE COATING; TRANSITION ELEMENT COMPOUNDS; TUNGSTEN COMPOUNDS; 400400* - Electrochemistry

Citation Formats

Koval, C A. (Chemical probes of charge transfer at semiconductor/liquid junctions). Technical report for May 15, 1984-January 15, 1985. United States: N. p., 1985. Web.
Koval, C A. (Chemical probes of charge transfer at semiconductor/liquid junctions). Technical report for May 15, 1984-January 15, 1985. United States.
Koval, C A. 1985. "(Chemical probes of charge transfer at semiconductor/liquid junctions). Technical report for May 15, 1984-January 15, 1985". United States.
@article{osti_5738618,
title = {(Chemical probes of charge transfer at semiconductor/liquid junctions). Technical report for May 15, 1984-January 15, 1985},
author = {Koval, C A},
abstractNote = {A study of the effects of surface energetics and surface oxide layers on the cyclic voltametry of metallocenes at nonilluminated p- and n-InP electrodes has been completed. Nearly ideal semiconductor/solution interfaces can be prepared, it was concluded, and the voltammetry of metallocenes is a way to probe electron transfer across this interface under different surface energetic conditions. Single crystals of WSe/sub 2/ were grown by chemical vapor transport. A computer program was written to collect voltametric data and calculated convoluted currents, and it is used to examine the kinetics of charge transfer across the semiconductor solution interface. (LEW)},
doi = {},
url = {https://www.osti.gov/biblio/5738618}, journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jan 01 00:00:00 EST 1985},
month = {Tue Jan 01 00:00:00 EST 1985}
}

Technical Report:
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