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Title: Consequence of condensed-phase formation in transient burning of TiH/sub x//KClO/sub 4/ in a closed system

Abstract

Transient burning of TiH/sub X//KClO/sub 4/ in a closed system is formulated including the effect of condensed species. Thermodynamic properties are evaluated using both BLAKE and TIGER computer codes. Three different equations of state for gaseous species are used and their effect on the burning rate is evaluated. For more accurate transient burning analysis, a pressure dependent covolume for gaseous species is generated. The effect of pressure dependent covolume as well as the condensed species on transient burning is evaluated. Both parameters are found to be important when the burning rate at high loading densities in a closed system is considered. At high loading densities, condensed species become important not only because of the their effect on thermodynamic properties but also due to the volume occupied by these species. 11 refs., 2 figs., 2 tabs.

Authors:
; ;
Publication Date:
Research Org.:
Sandia National Labs., Albuquerque, NM (USA)
OSTI Identifier:
5734697
Report Number(s):
SAND-89-0482C; CONF-8909113-3
ON: DE89013922
DOE Contract Number:  
AC04-76DP00789
Resource Type:
Conference
Resource Relation:
Conference: 14. international pyrotechnics seminar, Jersey, UK, 18-22 Sep 1989; Other Information: Portions of this document are illegible in microfiche products
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; POTASSIUM PERCHLORATES; COMBUSTION; TITANIUM HYDRIDES; B CODES; EQUATIONS OF STATE; PRESSURE DEPENDENCE; T CODES; THERMODYNAMIC PROPERTIES; ALKALI METAL COMPOUNDS; CHEMICAL REACTIONS; CHLORINE COMPOUNDS; COMPUTER CODES; EQUATIONS; HALOGEN COMPOUNDS; HYDRIDES; HYDROGEN COMPOUNDS; OXIDATION; OXYGEN COMPOUNDS; PERCHLORATES; PHYSICAL PROPERTIES; POTASSIUM COMPOUNDS; THERMOCHEMICAL PROCESSES; TITANIUM COMPOUNDS; TRANSITION ELEMENT COMPOUNDS; 400500* - Photochemistry

Citation Formats

Razani, A, Shahinpoor, M, and Hingorani-Norenberg, S L. Consequence of condensed-phase formation in transient burning of TiH/sub x//KClO/sub 4/ in a closed system. United States: N. p., 1989. Web.
Razani, A, Shahinpoor, M, & Hingorani-Norenberg, S L. Consequence of condensed-phase formation in transient burning of TiH/sub x//KClO/sub 4/ in a closed system. United States.
Razani, A, Shahinpoor, M, and Hingorani-Norenberg, S L. 1989. "Consequence of condensed-phase formation in transient burning of TiH/sub x//KClO/sub 4/ in a closed system". United States.
@article{osti_5734697,
title = {Consequence of condensed-phase formation in transient burning of TiH/sub x//KClO/sub 4/ in a closed system},
author = {Razani, A and Shahinpoor, M and Hingorani-Norenberg, S L},
abstractNote = {Transient burning of TiH/sub X//KClO/sub 4/ in a closed system is formulated including the effect of condensed species. Thermodynamic properties are evaluated using both BLAKE and TIGER computer codes. Three different equations of state for gaseous species are used and their effect on the burning rate is evaluated. For more accurate transient burning analysis, a pressure dependent covolume for gaseous species is generated. The effect of pressure dependent covolume as well as the condensed species on transient burning is evaluated. Both parameters are found to be important when the burning rate at high loading densities in a closed system is considered. At high loading densities, condensed species become important not only because of the their effect on thermodynamic properties but also due to the volume occupied by these species. 11 refs., 2 figs., 2 tabs.},
doi = {},
url = {https://www.osti.gov/biblio/5734697}, journal = {},
number = ,
volume = ,
place = {United States},
year = {Sun Jan 01 00:00:00 EST 1989},
month = {Sun Jan 01 00:00:00 EST 1989}
}

Conference:
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