Detection of nitro polynuclear aromatic compounds by surface-enhanced Raman spectrometry
The various nitro polynuclear aromatic compounds, including 1-nitropyrene, 9-nitroanthracene, 2-nitronaphthalene, and 2-nitrofluorene have been investigated by use of the surface-enhanced Raman scattering (SERS) spectrometry technique. Silver-coated substrates consisting of latex spheres on glass and filter paper and prolate SiO/sub 2/ posts on quartz were used. The limit of detection of 1-nitropyrene was found to be 0.3 ng. The SERS signals were enhanced over conventional Raman signals by a factor of 5 x 10/sup 6/ to 9 x 10/sup 6/ for 1-nitropyrene adsorbed on various SERS-active substrates. The production and practicality of SERS-active substrates with glass, paper, and quartz supports are discussed. 30 references, 6 figures, 1 table.
- Research Organization:
- Oak Ridge National Lab., TN
- DOE Contract Number:
- AC05-84OR21400
- OSTI ID:
- 5699757
- Journal Information:
- Anal. Chem.; (United States), Vol. 58:6
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
54 ENVIRONMENTAL SCIENCES
GLASS
SURFACE PROPERTIES
PAPER
POLYCYCLIC NITRO COMPOUNDS
RAMAN SPECTROSCOPY
QUARTZ
EXPERIMENTAL DATA
QUANTITATIVE CHEMICAL ANALYSIS
RAMAN SPECTRA
SURFACES
TRACE AMOUNTS
CHALCOGENIDES
CHEMICAL ANALYSIS
DATA
INFORMATION
LASER SPECTROSCOPY
MINERALS
NITRO COMPOUNDS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXIDE MINERALS
OXIDES
OXYGEN COMPOUNDS
SILICON COMPOUNDS
SILICON OXIDES
SPECTRA
SPECTROSCOPY
400104* - Spectral Procedures- (-1987)
520200 - Environment
Aquatic- Chemicals Monitoring & Transport- (-1989)
500200 - Environment
Atmospheric- Chemicals Monitoring & Transport- (-1989)