Difluorotris(perfluoralkyl)phosphoranes

Journal Article · Tue May 20 00:00:00 EDT 1986 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5676900

Semenii, V Ya; Stepanov, V A; Ignat'ev, N V; Furin, G G; Yagupol'skii, L M

By the electrochemical fluorination of trialkylphosphine oxides difluorotris(perfluoroalkyl)phosphoranes were obtained in yields which fell as the alkyl chain was lengthened. In the reactions of difluorotris(perfluoroalkyl)phosphoranes with hexamethyldisiloxane the corresponding phosphine oxides are formed, and in an HF medium these are converted back into the difluorophosphoranes.

• Research Organization: Institute of Organic Chemistry, Kiev, USSR
• OSTI ID: 5676900
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Vol. 55:12; Other Information: Translated from Zh. Obshch. Khim.; 55: No. 12, 2716-2720(Dec 1985)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
74 ATOMIC AND MOLECULAR PHYSICS
ORGANIC FLUORINE COMPOUNDS
NMR SPECTRA
SYNTHESIS
ORGANIC PHOSPHORUS COMPOUNDS
BINDING ENERGY
COUPLING CONSTANTS
ELECTRONS
FLUORINATION
FLUORINE 19
J-J COUPLING
PHOSPHINES
PHOSPHORUS 31
SILOXANES
VALENCE
CHEMICAL REACTIONS
COUPLING
ELEMENTARY PARTICLES
ENERGY
FERMIONS
FLUORINE ISOTOPES
HALOGENATION
INTERMEDIATE COUPLING
ISOTOPES
LEPTONS
LIGHT NUCLEI
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC SILICON COMPOUNDS
PHOSPHORUS COMPOUNDS
PHOSPHORUS ISOTOPES
SPECTRA
STABLE ISOTOPES
400201* - Chemical & Physicochemical Properties
640302 - Atomic
Molecular & Chemical Physics- Atomic & Molecular Properties & Theory