Scope and limitations of aliphatic Friedel-Crafts alkylations. Lewis acid catalyzed addition reactions of alkyl chlorides to carbon-carbon double bonds
Journal Article
·
· J. Org. Chem.; (United States)
Lewis acid catalyzed addition reactions of alkyl halides with unsaturated hydrocarbons have been studied. 1:1 addition products are formed if the addends dissociate faster than the corresponding products; otherwise, polymerization takes place. For reaction conditions under which these compounds exist mainly undissociated, solvolysis constants of model compounds can be used to predict the outcome of any such addition reactions if systems with considerable steric hindrance are excluded.
- Research Organization:
- Universitat Erlangen-Nurnberg, F.R. of Germany
- OSTI ID:
- 5654733
- Journal Information:
- J. Org. Chem.; (United States), Vol. 48:8
- Country of Publication:
- United States
- Language:
- English
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+2 more
Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
FRIEDEL-CRAFTS REACTION
USES
HYDROCARBONS
ALKYLATION
CATALYSIS
CHEMICAL BONDS
LEWIS ACIDS
ORGANIC CHLORINE COMPOUNDS
CHEMICAL REACTIONS
HYDROGEN COMPOUNDS
INORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
FRIEDEL-CRAFTS REACTION
USES
HYDROCARBONS
ALKYLATION
CATALYSIS
CHEMICAL BONDS
LEWIS ACIDS
ORGANIC CHLORINE COMPOUNDS
CHEMICAL REACTIONS
HYDROGEN COMPOUNDS
INORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)