Spectroscopic and ab initio studies of difluoromethyl radicals and cations
Journal Article
·
· Journal of Physical Chemistry
- National Institute of Standards and Technology, Gaithersburg, MD (United States); and others
The authors report molecular orbital calculations and experimental observations of the vibrational properties of CHF{sub 2} and CDF{sub 2} radicals and cations. This molecule is a reaction product of the atmospheric reaction of OH with CH{sub 2}F{sub 2}. REMPI measurements provide vibrational frequencies for the molecules, along with spectroscopic constants. Calculations give information on the structure, bond lengths and bond angles.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 555013
- Journal Information:
- Journal of Physical Chemistry, Vol. 96, Issue 2; Other Information: PBD: 23 Jan 1992
- Country of Publication:
- United States
- Language:
- English
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