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Title: Determination of solubility products of complex compounds of certain lanthanide and actinide diiodies with 18-crown-6 in tetrahydrofuran

Abstract

The existence of divalent americium in a tetrahydrofuran (THF) solution was proved for the first time. The values of the solubility products (SP) of the complex compounds with the composition of MeI{sub 2}{centered dot}18-crown-6 (Me = Sm, Eu, Yb, Am, Cf, Es, Fm) in the THF solutions were determined by the cocrystallization method. The SP values obtained are within (5.9-7.9){centered dot}10{sup {minus}12} and are close to the SP value for SrI{sub 2}{centered dot}10{sup {minus}12}, which indicates a similarity in the properties of these elements.

Authors:
; ;
Publication Date:
OSTI Identifier:
5523964
Resource Type:
Journal Article
Journal Name:
Soviet Radiochemistry (English Translation); (USA)
Additional Journal Information:
Journal Volume: 30:1; Other Information: Translated from Radiokhimiya; 30: No. 1, 56-59(Jan-Feb 1988); Journal ID: ISSN 0038-576X
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; 36 MATERIALS SCIENCE; ACTINIDE COMPLEXES; RADIOCHEMICAL ANALYSIS; IODIDES; POLYETHYLENE GLYCOLS; RARE EARTH COMPLEXES; ALPHA SPECTRA; AMERICIUM 243; AMERICIUM IODIDES; BARIUM 140; CALCIUM 47; CALIFORNIUM IODIDES; COPRECIPITATION; CRYSTALLIZATION; EINSTEINIUM 253; EINSTEINIUM IODIDES; EUROPIUM 154; EUROPIUM IODIDES; FERMIUM 254; FERMIUM IODIDES; GAMMA SPECTRA; SAMARIUM 153; SAMARIUM IODIDES; SOLUBILITY; SOLVENT PROPERTIES; STRONTIUM 85; TETRAHYDROFURAN; TRACER TECHNIQUES; VALENCE; YTTERBIUM 169; YTTERBIUM IODIDES; ACTINIDE COMPOUNDS; ACTINIDE ISOTOPES; ACTINIDE NUCLEI; ALCOHOLS; ALKALINE EARTH ISOTOPES; ALPHA DECAY RADIOISOTOPES; AMERICIUM COMPOUNDS; AMERICIUM ISOTOPES; BARIUM ISOTOPES; BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; BETA-PLUS DECAY RADIOISOTOPES; CALCIUM ISOTOPES; CALIFORNIUM COMPOUNDS; CHEMICAL ANALYSIS; COMPLEXES; DAYS LIVING RADIOISOTOPES; EINSTEINIUM COMPOUNDS; EINSTEINIUM ISOTOPES; ELECTRON CAPTURE RADIOISOTOPES; EUROPIUM COMPOUNDS; EUROPIUM ISOTOPES; EVEN-EVEN NUCLEI; EVEN-ODD NUCLEI; FERMIUM COMPOUNDS; FERMIUM ISOTOPES; FURANS; GLYCOLS; HALIDES; HALOGEN COMPOUNDS; HEAVY NUCLEI; HETEROCYCLIC COMPOUNDS; HOURS LIVING RADIOISOTOPES; HYDROXY COMPOUNDS; INTERMEDIATE MASS NUCLEI; INTERNAL CONVERSION RADIOISOTOPES; IODINE COMPOUNDS; ISOMERIC TRANSITION ISOTOPES; ISOTOPE APPLICATIONS; ISOTOPES; MINUTES LIVING RADIOISOTOPES; NUCLEI; ODD-EVEN NUCLEI; ODD-ODD NUCLEI; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; ORGANIC POLYMERS; PHASE TRANSFORMATIONS; POLYMERS; PRECIPITATION; QUANTITATIVE CHEMICAL ANALYSIS; RADIOISOTOPES; RARE EAR; RARE EARTH COMPOUNDS; RARE EARTH ISOTOPES; RARE EARTH NUCLEI; SAMARIUM COMPOUNDS; SAMARIUM ISOTOPES; SEPARATION PROCESSES; SPECTRA; STRONTIUM ISOTOPES; TRANSPLUTONIUM COMPOUNDS; TRANSURANIUM COMPOUNDS; YEARS LIVI; YEARS LIVING RADIOISOTOPES; YTTERBIUM COMPOUNDS; YTTERBIUM ISOTOPES; 400101* - Activation, Nuclear Reaction, Radiometric & Radiochemical Procedures; 400102 - Chemical & Spectral Procedures; 400702 - Radiochemistry & Nuclear Chemistry- Properties of Radioactive Materials; 360602 - Other Materials- Structure & Phase Studies

Citation Formats

Mikheev, N B, Kamenskaya, A N, and Kulyukhin, S A. Determination of solubility products of complex compounds of certain lanthanide and actinide diiodies with 18-crown-6 in tetrahydrofuran. United States: N. p., 1988. Web.
Mikheev, N B, Kamenskaya, A N, & Kulyukhin, S A. Determination of solubility products of complex compounds of certain lanthanide and actinide diiodies with 18-crown-6 in tetrahydrofuran. United States.
Mikheev, N B, Kamenskaya, A N, and Kulyukhin, S A. 1988. "Determination of solubility products of complex compounds of certain lanthanide and actinide diiodies with 18-crown-6 in tetrahydrofuran". United States.
@article{osti_5523964,
title = {Determination of solubility products of complex compounds of certain lanthanide and actinide diiodies with 18-crown-6 in tetrahydrofuran},
author = {Mikheev, N B and Kamenskaya, A N and Kulyukhin, S A},
abstractNote = {The existence of divalent americium in a tetrahydrofuran (THF) solution was proved for the first time. The values of the solubility products (SP) of the complex compounds with the composition of MeI{sub 2}{centered dot}18-crown-6 (Me = Sm, Eu, Yb, Am, Cf, Es, Fm) in the THF solutions were determined by the cocrystallization method. The SP values obtained are within (5.9-7.9){centered dot}10{sup {minus}12} and are close to the SP value for SrI{sub 2}{centered dot}10{sup {minus}12}, which indicates a similarity in the properties of these elements.},
doi = {},
url = {https://www.osti.gov/biblio/5523964}, journal = {Soviet Radiochemistry (English Translation); (USA)},
issn = {0038-576X},
number = ,
volume = 30:1,
place = {United States},
year = {Thu Sep 01 00:00:00 EDT 1988},
month = {Thu Sep 01 00:00:00 EDT 1988}
}