Synthesis and characterization of hexakis(alkyl isocyanide) and hexakis(aryl isocyanide) complexes of technetium(I)

Journal Article · Wed Sep 28 00:00:00 EDT 1983 · Inorg. Chem.; (United States)

DOI:https://doi.org/10.1021/ic00162a007· OSTI ID:5506629

Abrams, M J ^[1]; Davison, A; Jones, A G; Costello, C E; Pang, H

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1. Massachusetts Inst. of Tech., Cambridge

The complexes, hexakis(alkyl isocyanide) technetium(I) hexafluorophosphate (Tc(CNR)/sub 6/)PF/sub 6/ (where R = tert-butyl, methyl, cyclohexyl, and phenyl), have been prepared by reduction of the pertechnetate ion with aqueous sodium dithionite (Na/sub 2/S/sub 2/O/sub 4/) in the presence of the isocyanide ligands. These complexes have been characterized by elemental analysis, optical, ir, and /sup 1/H NMR spectroscopy, conductance, cyclic voltammetry, and field desorption mass spectrometry.

• OSTI ID: 5506629
• Journal Information: Inorg. Chem.; (United States), Vol. 22:20
• Country of Publication: United States
• Language: English

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
62 RADIOLOGY AND NUCLEAR MEDICINE
TECHNETIUM COMPLEXES
CHEMICAL PREPARATION
STRUCTURAL CHEMICAL ANALYSIS
AMMONIUM COMPOUNDS
AQUEOUS SOLUTIONS
AROMATICS
COMPARATIVE EVALUATIONS
CYANIDES
CYCLOALKANES
ELECTRIC CONDUCTIVITY
EXPERIMENTAL DATA
FLUORINE COMPOUNDS
INFRARED SPECTRA
MASS SPECTRA
NMR SPECTRA
OPTICAL SPECTROMETERS
OXYGEN COMPOUNDS
PERTECHNETATES
PH VALUE
PHOSPHATES
RECRYSTALLIZATION
SODIUM COMPOUNDS
SULFUR COMPOUNDS
VOLTAMETRY
ALKALI METAL COMPOUNDS
ALKANES
COMPLEXES
DATA
DISPERSIONS
ELECTRICAL PROPERTIES
HALOGEN COMPOUNDS
HYDROCARBONS
INFORMATION
MEASURING INSTRUMENTS
MIXTURES
NUMERICAL DATA
ORGANIC COMPOUNDS
PHOSPHORUS COMPOUNDS
PHYSICAL PROPERTIES
SOLUTIONS
SPECTRA
SPECTROMETERS
SYNTHESIS
TECHNETIUM COMPOUNDS
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
400702* - Radiochemistry & Nuclear Chemistry- Properties of Radioactive Materials
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