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Title: Identification by stopped-exchange solution /sup 31/P NMR spectroscopy of the stepwise formation of (AgL/sub n/)PF/sub 6/ (n = 1-4). Comparison of metal-phosphorus coupling constants for triphenylphosphine and 5-phenyldibenzophosphole

Abstract

The coordination properties of 5-phenyldibenzophosphate (PhDBP) have been studied extensively. The stepwise formation of (L/sub n/Ag)/sup +/PF/sub 6//sup -/ (n = 1-4) for L = PhDBP and PhP/sub 3/ observed in situ by stopped-exchange solution /sup 31/P NMR spectroscopy is reported herein. The relative coordinating properties of PhDBP and PhP/sub 3/ are compared. 21 references, 1 figure, 2 tables.

Authors:
; ;
Publication Date:
Research Org.:
Univ. of Guelph, Ontario
OSTI Identifier:
5477614
Resource Type:
Journal Article
Journal Name:
Inorg. Chem.; (United States)
Additional Journal Information:
Journal Volume: 26:25
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; AROMATICS; MOLECULAR STRUCTURE; ORGANIC PHOSPHORUS COMPOUNDS; SILVER COMPLEXES; CHEMICAL SHIFT; EXPERIMENTAL DATA; NMR SPECTRA; PHOSPHORUS 31; COMPLEXES; DATA; INFORMATION; ISOTOPES; LIGHT NUCLEI; NUCLEI; NUMERICAL DATA; ODD-EVEN NUCLEI; ORGANIC COMPOUNDS; PHOSPHORUS ISOTOPES; SPECTRA; STABLE ISOTOPES; TRANSITION ELEMENT COMPLEXES; 400201* - Chemical & Physicochemical Properties; 400202 - Isotope Effects, Isotope Exchange, & Isotope Separation

Citation Formats

Alyea, E C, Malito, J, and Nelson, J H. Identification by stopped-exchange solution /sup 31/P NMR spectroscopy of the stepwise formation of (AgL/sub n/)PF/sub 6/ (n = 1-4). Comparison of metal-phosphorus coupling constants for triphenylphosphine and 5-phenyldibenzophosphole. United States: N. p., 1987. Web. doi:10.1021/ic00272a032.
Alyea, E C, Malito, J, & Nelson, J H. Identification by stopped-exchange solution /sup 31/P NMR spectroscopy of the stepwise formation of (AgL/sub n/)PF/sub 6/ (n = 1-4). Comparison of metal-phosphorus coupling constants for triphenylphosphine and 5-phenyldibenzophosphole. United States. https://doi.org/10.1021/ic00272a032
Alyea, E C, Malito, J, and Nelson, J H. 1987. "Identification by stopped-exchange solution /sup 31/P NMR spectroscopy of the stepwise formation of (AgL/sub n/)PF/sub 6/ (n = 1-4). Comparison of metal-phosphorus coupling constants for triphenylphosphine and 5-phenyldibenzophosphole". United States. https://doi.org/10.1021/ic00272a032.
@article{osti_5477614,
title = {Identification by stopped-exchange solution /sup 31/P NMR spectroscopy of the stepwise formation of (AgL/sub n/)PF/sub 6/ (n = 1-4). Comparison of metal-phosphorus coupling constants for triphenylphosphine and 5-phenyldibenzophosphole},
author = {Alyea, E C and Malito, J and Nelson, J H},
abstractNote = {The coordination properties of 5-phenyldibenzophosphate (PhDBP) have been studied extensively. The stepwise formation of (L/sub n/Ag)/sup +/PF/sub 6//sup -/ (n = 1-4) for L = PhDBP and PhP/sub 3/ observed in situ by stopped-exchange solution /sup 31/P NMR spectroscopy is reported herein. The relative coordinating properties of PhDBP and PhP/sub 3/ are compared. 21 references, 1 figure, 2 tables.},
doi = {10.1021/ic00272a032},
url = {https://www.osti.gov/biblio/5477614}, journal = {Inorg. Chem.; (United States)},
number = ,
volume = 26:25,
place = {United States},
year = {Wed Dec 16 00:00:00 EST 1987},
month = {Wed Dec 16 00:00:00 EST 1987}
}