Periodic trends in the hydrodenitrogenation activity of carbon-supported transition metal sulfide catalysts

Journal Article · Fri Jan 01 00:00:00 EST 1988 · J. Catal.; (United States)

DOI:https://doi.org/10.1016/0021-9517(88)90201-1· OSTI ID:5463817

Eijsbouts, S; De Beer, V H.J.; Prins, R

Periodic trends of transition metals for the catalysis of reactions such as hydrogenation, hydrogenolysis, isomerization and hydrogen oxidation have been well studied. When activity versus position of the transition metal in the periodic table is plotted, quite often these trends are manifested in the form of so-called volcano-type curves. In the present study, the authors have chosen the HDN of quinoline at moderately high pressure as a model reaction, and they have used the same carbon-supported transition metal sulfide catalysts studied by Vissers et al. Results are shown for the following transition metals: V, Cr, Mn, Fe, Co, Ni, Mo, Ru, Rh, Pd, W, Re, Os, Ir, and Pt. 9 references.

• Research Organization: Eindhoven Univ. of Technology, Netherlands
• OSTI ID: 5463817
• Journal Information: J. Catal.; (United States), Vol. 109:1
• Country of Publication: United States
• Language: English

Related Subjects

02 PETROLEUM
CHROMIUM SULFIDES
CATALYTIC EFFECTS
COBALT SULFIDES
IRIDIUM COMPOUNDS
IRON SULFIDES
MANGANESE SULFIDES
MOLYBDENUM SULFIDES
NICKEL SULFIDES
OSMIUM SULFIDES
PALLADIUM SULFIDES
PLATINUM SULFIDES
QUINOLINES
DENITRIFICATION
RHENIUM SULFIDES
RHODIUM SULFIDES
RUTHENIUM SULFIDES
TUNGSTEN SULFIDES
VANADIUM SULFIDES
AUTOCLAVES
CARBON
CATALYST SUPPORTS
CATALYSTS
CHEMICAL PREPARATION
HYDROGEN
HYDROGEN SULFIDES
SULFIDES
SURFACE AREA
AROMATICS
AZAARENES
AZINES
CHALCOGENIDES
CHEMICAL REACTIONS
CHROMIUM COMPOUNDS
COBALT COMPOUNDS
ELEMENTS
HETEROCYCLIC COMPOUNDS
HYDROGEN COMPOUNDS
IRON COMPOUNDS
MANGANESE COMPOUNDS
MOLYBDENUM COMPOUNDS
NICKEL COMPOUNDS
NONMETALS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OSMIUM COMPOUNDS
PALLADIUM COMPOUNDS
PLATINUM COMPOUNDS
PYRIDINES
REFRACTORY METAL COMPOUNDS
RHENIUM COMPOUNDS
RHODIUM COMPOUNDS
RUTHENIUM COMPOUNDS
SULFUR COMPOUNDS
SURFACE PROPERTIES
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
TUNGSTEN COMPOUNDS
VANADIUM COMPOUNDS
020400* - Petroleum- Processing