Volumetric properties of cyclic hydrocarbons in tetrachloromethane at 25{degrees}C

Matteoli, E; Lepori, L; Spanedda, A

doi:10.1007/BF00972749

Title: Volumetric properties of cyclic hydrocarbons in tetrachloromethane at 25{degrees}C

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Abstract

By means of a vibrating-tube densimeter, the densities at 25{degrees}C have been determined for binary mixtures of tetrachloromethane with a liquid (cyclodecane, cis-decahydronaphthalene, trans-decahydronaphthalene, bicyclohexyl, pentane) or a solid hydrocarbon (cyclododecane, cyclopentadecane, norbornane, adamantane, octahydro-4,7-methano-1H-indene). Excess molar volumes have been obtained in the whole mole fraction range for mixtures containing a liquid hydrocarbon. For solid cycloalkanes, apparent molar volumes have been evaluated in the whole range of miscibility. The partial molar volumes at infinite dilution {bar V} have been calculated for all examined cycloalkanes and compared with those of n-alkanes. The dependence of {bar V} upon the size and shape of the ring or cage structure of the solute is discussed. The capability of the Flory theory to reproduce V{sup E} for these mixtures is also tested.

Authors:: Matteoli, E; Lepori, L; Spanedda, A

Publication Date:: Sun May 01 00:00:00 EDT 1994

Sponsoring Org.:: USDOE

OSTI Identifier:: 54563

Resource Type:: Journal Article

Journal Name:: Journal of Solution Chemistry

Additional Journal Information:: Journal Volume: 23; Journal Issue: 5; Other Information: PBD: May 1994

Country of Publication:: United States

Language:: English

Subject:: 40 CHEMISTRY; CYCLOALKANES; PARTIAL MOLAL VOLUME; NAPHTHALENE; INDENE

Citation Formats


                    Matteoli, E, Lepori, L, and Spanedda, A. Volumetric properties of cyclic hydrocarbons in tetrachloromethane at 25{degrees}C.  United States: N. p., 1994. 
        Web.  doi:10.1007/BF00972749.

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                    Matteoli, E, Lepori, L, & Spanedda, A. Volumetric properties of cyclic hydrocarbons in tetrachloromethane at 25{degrees}C.  United States.  https://doi.org/10.1007/BF00972749

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                    Matteoli, E, Lepori, L, and Spanedda, A. 1994.  
        "Volumetric properties of cyclic hydrocarbons in tetrachloromethane at 25{degrees}C".  United States.  https://doi.org/10.1007/BF00972749.

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@article{osti_54563,

  title        = {Volumetric properties of cyclic hydrocarbons in tetrachloromethane at 25{degrees}C},

  author       = {Matteoli, E and Lepori, L and Spanedda, A},

  abstractNote = {By means of a vibrating-tube densimeter, the densities at 25{degrees}C have been determined for binary mixtures of tetrachloromethane with a liquid (cyclodecane, cis-decahydronaphthalene, trans-decahydronaphthalene, bicyclohexyl, pentane) or a solid hydrocarbon (cyclododecane, cyclopentadecane, norbornane, adamantane, octahydro-4,7-methano-1H-indene). Excess molar volumes have been obtained in the whole mole fraction range for mixtures containing a liquid hydrocarbon. For solid cycloalkanes, apparent molar volumes have been evaluated in the whole range of miscibility. The partial molar volumes at infinite dilution {bar V} have been calculated for all examined cycloalkanes and compared with those of n-alkanes. The dependence of {bar V} upon the size and shape of the ring or cage structure of the solute is discussed. The capability of the Flory theory to reproduce V{sup E} for these mixtures is also tested.},

  doi          = {10.1007/BF00972749},

  url          = {https://www.osti.gov/biblio/54563},
  journal      = {Journal of Solution Chemistry},
number       = 5,

  volume       = 23,

  place        = {United States},

  year         = {Sun May 01 00:00:00 EDT 1994},

  month        = {Sun May 01 00:00:00 EDT 1994}

}

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