skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Isotope effects in solution thermodynamics: Excess properties in solution of isotopomers

Abstract

In this review the authors consider recent studies of isotope effects (IE's) on the physical properties of solution, such as vapor pressure, molar volume, compressibility, etc. Such IE's are of interest for two reasons: first, because they can sometimes be capitalized to separation processes, and samples of separated isotopes may be scientifically and commercially valuable and second, and more importantly to use, because the sign and magnitude of condensed phase isotope effects (CPIE's) are closely related to the nature of the intermolecular forces in liquids and solutions. Thus, appropriate IE data can probe the nature of molecular interaction and structure. 91 refs.

Authors:
 [1];  [2];  [3]
  1. Atomic Energy Research Inst., Budapest (Hungary). Central Research Inst. for Physics
  2. New Univ. of Lisbon (Portugal)
  3. Univ. of Tennessee, Knoxville, TN (United States). Chemistry Dept.
Publication Date:
OSTI Identifier:
5445017
Resource Type:
Journal Article
Journal Name:
Chemical Reviews; (United States)
Additional Journal Information:
Journal Volume: 93:8; Journal ID: ISSN 0009-2665
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; DEUTERIUM; ISOTOPE EFFECTS; GASES; SEPARATION PROCESSES; THERMODYNAMIC PROPERTIES; SOLUTIONS; AMMONIA; ARGON; BENZENE; CYCLOHEXANE; DEUTERIUM COMPOUNDS; FREE ENERGY; HYDROCHLORIC ACID; HYDROGEN SULFIDES; KRYPTON; METHANE; METHANOL; MOLECULAR STRUCTURE; ALCOHOLS; ALKANES; AROMATICS; CHALCOGENIDES; CHLORINE COMPOUNDS; CYCLOALKANES; DISPERSIONS; ELEMENTS; ENERGY; FLUIDS; HALOGEN COMPOUNDS; HYDRIDES; HYDROCARBONS; HYDROGEN COMPOUNDS; HYDROGEN ISOTOPES; HYDROXY COMPOUNDS; INORGANIC ACIDS; ISOTOPES; LIGHT NUCLEI; MIXTURES; NITROGEN COMPOUNDS; NITROGEN HYDRIDES; NONMETALS; NUCLEI; ODD-ODD NUCLEI; ORGANIC COMPOUNDS; PHYSICAL PROPERTIES; RARE GASES; STABLE ISOTOPES; SULFIDES; SULFUR COMPOUNDS; 400202* - Isotope Effects, Isotope Exchange, & Isotope Separation; 400105 - Separation Procedures

Citation Formats

Jancso, G, Rebelo, L P.N., and Van Hook, W A. Isotope effects in solution thermodynamics: Excess properties in solution of isotopomers. United States: N. p., 1993. Web. doi:10.1021/cr00024a004.
Jancso, G, Rebelo, L P.N., & Van Hook, W A. Isotope effects in solution thermodynamics: Excess properties in solution of isotopomers. United States. https://doi.org/10.1021/cr00024a004
Jancso, G, Rebelo, L P.N., and Van Hook, W A. 1993. "Isotope effects in solution thermodynamics: Excess properties in solution of isotopomers". United States. https://doi.org/10.1021/cr00024a004.
@article{osti_5445017,
title = {Isotope effects in solution thermodynamics: Excess properties in solution of isotopomers},
author = {Jancso, G and Rebelo, L P.N. and Van Hook, W A},
abstractNote = {In this review the authors consider recent studies of isotope effects (IE's) on the physical properties of solution, such as vapor pressure, molar volume, compressibility, etc. Such IE's are of interest for two reasons: first, because they can sometimes be capitalized to separation processes, and samples of separated isotopes may be scientifically and commercially valuable and second, and more importantly to use, because the sign and magnitude of condensed phase isotope effects (CPIE's) are closely related to the nature of the intermolecular forces in liquids and solutions. Thus, appropriate IE data can probe the nature of molecular interaction and structure. 91 refs.},
doi = {10.1021/cr00024a004},
url = {https://www.osti.gov/biblio/5445017}, journal = {Chemical Reviews; (United States)},
issn = {0009-2665},
number = ,
volume = 93:8,
place = {United States},
year = {Wed Dec 01 00:00:00 EST 1993},
month = {Wed Dec 01 00:00:00 EST 1993}
}