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Title: {ital In-situ} x-ray investigation of hydrogen charging in thin film bimetallic electrodes

Abstract

Hydrogen uptake and discharge by thin metallic films under potentiostatic control was studied using x-ray diffraction at the National Synchrotron Light Source (NSLS). The formation of metal-hydrogen phases in Pd, Pd-capped Nb and Pd/Nb multilayer electrode structures was deduced from x-ray diffraction data and correlated with the cyclic voltammetry (CV) peaks. The x-ray data was also used to construct a plot of the hydrogen concentration as a function of cell potential for a multilayered thin film. {copyright} {ital 1997 Materials Research Society.}

Authors:
; ; ; ; ; ;  [1]
  1. Department of Physics, Brookhaven National Laboratory, Upton, New York 11973 (United States)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
OSTI Identifier:
542188
DOE Contract Number:  
AC02-76CH00016
Resource Type:
Journal Article
Journal Name:
Journal of Materials Research
Additional Journal Information:
Journal Volume: 12; Journal Issue: 8; Other Information: PBD: Aug 1997
Country of Publication:
United States
Language:
English
Subject:
08 HYDROGEN FUEL; 40 CHEMISTRY; 36 MATERIALS SCIENCE; THIN FILMS; HYDROGEN STORAGE; ELECTRODES; PALLADIUM; NIOBIUM; HYDRIDES; ELECTROCHEMICAL CELLS; X-RAY DIFFRACTION; PHASE STUDIES; LATTICE PARAMETERS

Citation Formats

Jisrawi, N M, Wiesmann, H, Ruckman, M W, Thurston, T R, Reisfeld, G, Ocko, B M, and Strongin, M. {ital In-situ} x-ray investigation of hydrogen charging in thin film bimetallic electrodes. United States: N. p., 1997. Web. doi:10.1557/JMR.1997.0280.
Jisrawi, N M, Wiesmann, H, Ruckman, M W, Thurston, T R, Reisfeld, G, Ocko, B M, & Strongin, M. {ital In-situ} x-ray investigation of hydrogen charging in thin film bimetallic electrodes. United States. https://doi.org/10.1557/JMR.1997.0280
Jisrawi, N M, Wiesmann, H, Ruckman, M W, Thurston, T R, Reisfeld, G, Ocko, B M, and Strongin, M. 1997. "{ital In-situ} x-ray investigation of hydrogen charging in thin film bimetallic electrodes". United States. https://doi.org/10.1557/JMR.1997.0280.
@article{osti_542188,
title = {{ital In-situ} x-ray investigation of hydrogen charging in thin film bimetallic electrodes},
author = {Jisrawi, N M and Wiesmann, H and Ruckman, M W and Thurston, T R and Reisfeld, G and Ocko, B M and Strongin, M},
abstractNote = {Hydrogen uptake and discharge by thin metallic films under potentiostatic control was studied using x-ray diffraction at the National Synchrotron Light Source (NSLS). The formation of metal-hydrogen phases in Pd, Pd-capped Nb and Pd/Nb multilayer electrode structures was deduced from x-ray diffraction data and correlated with the cyclic voltammetry (CV) peaks. The x-ray data was also used to construct a plot of the hydrogen concentration as a function of cell potential for a multilayered thin film. {copyright} {ital 1997 Materials Research Society.}},
doi = {10.1557/JMR.1997.0280},
url = {https://www.osti.gov/biblio/542188}, journal = {Journal of Materials Research},
number = 8,
volume = 12,
place = {United States},
year = {Fri Aug 01 00:00:00 EDT 1997},
month = {Fri Aug 01 00:00:00 EDT 1997}
}