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Title: Durability of metals from archaeological objects, metal meteorites, and native metals

Abstract

Metal durability is an important consideration in the multi-barrier nuclear waste storage concept. This study summarizes the ancient metals, the environments, and factors which appear to have contributed to metal longevity. Archaeological and radiochemical dating suggest that human use of metals began in the period 6000 to 7000 BC. Gold is clearly the most durable, but many objects fashioned from silver, copper, bronze, iron, lead, and tin have survived for several thousand years. Dry environments, such as tombs, appear to be optimum for metal preservation, but some metals have survived in shipwrecks for over a thousand years. The metal meteorites are Fe-base alloys with 5 to 60 wt% Ni and minor amounts of Co, I, and S. Some meteoritic masses with ages estimated to be 5,000 to 20,000 years have weathered very little, while other masses from the same meteorites are in advanced stages of weathering. Native metals are natural metallic ores. Approximately five million tonnes were mined from native copper deposits in Michigan. Copper masses from the Michigan deposits were transported by the Pleistocene glaciers. Areas on the copper surfaces which appear to represent glacial abrasion show minimal corrosion. Dry cooling tower technology has demonstrated that in pollution-free moistmore » environments, metals fare better at temperatures above than below the dewpoint. Thus, in moderate temperature regimes, elevated temperatures may be useful rather than detrimental for exposures of metal to air. In liquid environments, relatively complex radiolysis reactions can occur, particularly where multiple species are present. A dry environment largely obviates radiolysis effects.« less

Authors:
;
Publication Date:
Research Org.:
Battelle Pacific Northwest Labs., Richland, WA (United States)
OSTI Identifier:
5406419
Report Number(s):
PNL-3198
TRN: 80-007629
DOE Contract Number:  
EY-76-C-06-1830
Resource Type:
Technical Report
Country of Publication:
United States
Language:
English
Subject:
58 GEOSCIENCES; 12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES; 36 MATERIALS SCIENCE; ARCHAEOLOGICAL SPECIMENS; WEATHERING; METALS; METEORITES; RADIOACTIVE WASTE STORAGE; CONTAINERS; CORROSION; MOISTURE; CHEMICAL REACTIONS; ELEMENTS; MANAGEMENT; STORAGE; WASTE MANAGEMENT; WASTE STORAGE; 580100* - Geology & Hydrology- (-1989); 052002 - Nuclear Fuels- Waste Disposal & Storage; 360105 - Metals & Alloys- Corrosion & Erosion

Citation Formats

Johnson, Jr, A B, and Francis, B. Durability of metals from archaeological objects, metal meteorites, and native metals. United States: N. p., 1980. Web. doi:10.2172/5406419.
Johnson, Jr, A B, & Francis, B. Durability of metals from archaeological objects, metal meteorites, and native metals. United States. https://doi.org/10.2172/5406419
Johnson, Jr, A B, and Francis, B. 1980. "Durability of metals from archaeological objects, metal meteorites, and native metals". United States. https://doi.org/10.2172/5406419. https://www.osti.gov/servlets/purl/5406419.
@article{osti_5406419,
title = {Durability of metals from archaeological objects, metal meteorites, and native metals},
author = {Johnson, Jr, A B and Francis, B},
abstractNote = {Metal durability is an important consideration in the multi-barrier nuclear waste storage concept. This study summarizes the ancient metals, the environments, and factors which appear to have contributed to metal longevity. Archaeological and radiochemical dating suggest that human use of metals began in the period 6000 to 7000 BC. Gold is clearly the most durable, but many objects fashioned from silver, copper, bronze, iron, lead, and tin have survived for several thousand years. Dry environments, such as tombs, appear to be optimum for metal preservation, but some metals have survived in shipwrecks for over a thousand years. The metal meteorites are Fe-base alloys with 5 to 60 wt% Ni and minor amounts of Co, I, and S. Some meteoritic masses with ages estimated to be 5,000 to 20,000 years have weathered very little, while other masses from the same meteorites are in advanced stages of weathering. Native metals are natural metallic ores. Approximately five million tonnes were mined from native copper deposits in Michigan. Copper masses from the Michigan deposits were transported by the Pleistocene glaciers. Areas on the copper surfaces which appear to represent glacial abrasion show minimal corrosion. Dry cooling tower technology has demonstrated that in pollution-free moist environments, metals fare better at temperatures above than below the dewpoint. Thus, in moderate temperature regimes, elevated temperatures may be useful rather than detrimental for exposures of metal to air. In liquid environments, relatively complex radiolysis reactions can occur, particularly where multiple species are present. A dry environment largely obviates radiolysis effects.},
doi = {10.2172/5406419},
url = {https://www.osti.gov/biblio/5406419}, journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jan 01 00:00:00 EST 1980},
month = {Tue Jan 01 00:00:00 EST 1980}
}