Isotachophoresis: a versatile technique for the determination of ionic species. [2-(5-cyanotetrazolato) pentammine Co(III) perchlorate]

Conference · Sat Jan 01 00:00:00 EST 1983

OSTI ID:5396074

McCarthy, J P; Kapsch, D M; Kinard, C

Isotachophoresis (ITP), a method for the electrophoretic separation and quantification of ionic species is currently available at Mound. The technique is applicable for the analysis of virtually any system of charged species. The theory and instrumentation required for this technique are discussed. The application currently being investigated at Mound is the determination of the amide derivative present as an ionic impurity in the explosive 2(5-cyanotetrazolato)pentaamine Co (III) perchlorate. Results indicate 2 to 10% amide content in CP dependent upon the lot analyzed. This analysis is discussed along with other ITP applications.

• Research Organization: Monsanto Research Corp., Miamisburg, OH (USA). Mound
• DOE Contract Number: AC04-76DP00053
• OSTI ID: 5396074
• Report Number(s): MLM-3114(OP); CONF-8310111-10; ON: DE84002841
• Resource Relation: Conference: 11. DOE annual compatibility meeting, Livermore, CA, USA, 18 Oct 1983; Other Information: Portions are illegible in microfiche products
• Country of Publication: United States
• Language: English

Related Subjects

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEFENSE
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CHEMICAL EXPLOSIVES
CHEMICAL ANALYSIS
AMIDES
AMMINES
COBALT COMPLEXES
ELECTROPHORESIS
IMPURITIES
PERCHLORATES
CHLORINE COMPOUNDS
COMPLEXES
EXPLOSIVES
HALOGEN COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXYGEN COMPOUNDS
TRANSITION ELEMENT COMPLEXES
450100* - Military Technology
Weaponry
& National Defense- Chemical Explosions & Explosives
400102 - Chemical & Spectral Procedures