Influence of the solvent on the interaction of phenyl isocyanate with proton donors, catalyzed by copper(II) acetylacetonate
Journal Article
·
· Kinet. Catal. (Engl. Transl.); (United States)
OSTI ID:5306446
The influence of the medium on the noncatalytic and copper(II)-acetylacetonate-catalyzed interaction of phenyl isocyanate with n-butanol under conditions of an excess of isocyanate was investigated. It was shown that the product of superequimolar conversion of isocyanate is n-butyl-..cap alpha.., ..gamma..-diphenylallophanate. The kinetic and thermodynamic peculiarities of the process of formation of urethane and allophanate in various solvents are discussed.
- Research Organization:
- Institute of Organic Chemistry, Kiev (USSR)
- OSTI ID:
- 5306446
- Journal Information:
- Kinet. Catal. (Engl. Transl.); (United States), Vol. 28:2; Other Information: Translated from Kinet. Katal.; 28: No. 2, 342-346(Mar-Apr 1987)
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
BUTANOLS
HETEROGENEOUS CATALYSIS
COPPER COMPLEXES
CATALYTIC EFFECTS
ISOCYANATES
ORGANIC SOLVENTS
COMPARATIVE EVALUATIONS
MATERIALS TESTING
2-3-PENTANEDIONE
ACETONITRILE
ACETYLACETONE
ACTIVATION ENERGY
CHEMICAL REACTION KINETICS
CHLORINATED AROMATIC HYDROCARBONS
SOLVENT PROPERTIES
THERMODYNAMICS
URETHANE
ALCOHOLS
AROMATICS
CARBAMATES
CARBONIC ACID DERIVATIVES
CARBOXYLIC ACID SALTS
CATALYSIS
CHELATING AGENTS
COMPLEXES
ENERGY
HALOGENATED AROMATIC HYDROCARBONS
HYDROXY COMPOUNDS
KETONES
KINETICS
NITRILES
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
REACTION KINETICS
REAGENTS
SOLVENTS
TESTING
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
BUTANOLS
HETEROGENEOUS CATALYSIS
COPPER COMPLEXES
CATALYTIC EFFECTS
ISOCYANATES
ORGANIC SOLVENTS
COMPARATIVE EVALUATIONS
MATERIALS TESTING
2-3-PENTANEDIONE
ACETONITRILE
ACETYLACETONE
ACTIVATION ENERGY
CHEMICAL REACTION KINETICS
CHLORINATED AROMATIC HYDROCARBONS
SOLVENT PROPERTIES
THERMODYNAMICS
URETHANE
ALCOHOLS
AROMATICS
CARBAMATES
CARBONIC ACID DERIVATIVES
CARBOXYLIC ACID SALTS
CATALYSIS
CHELATING AGENTS
COMPLEXES
ENERGY
HALOGENATED AROMATIC HYDROCARBONS
HYDROXY COMPOUNDS
KETONES
KINETICS
NITRILES
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
REACTION KINETICS
REAGENTS
SOLVENTS
TESTING
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties