Organosilicon derivatives of selenium containing the Se(CH/sub 2/)/sub n/ Si group

Journal Article · Tue Feb 10 00:00:00 EST 1987 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5286621

Voronkov, M G; Sorokin, M S

Methods were developed for the synthesis of previously unknown organosilicon derivatives of selenium: organyl (trimethyloxysilyl)alkyl selenides, organyl silatranylalkyl selenides, organylmethyl(silatranylmethyl)selenonium iodides, and organyl 2-(trifluorosilyl)ethyl selenides. Some of their chemical reactions, their /sup 1/H NMR and IR spectra, and their toxicities were studied. Alkanethiols catalyze the photochemical addition of selenols to trimethoxyvinylsilane. In competitive reactions of the photochemical addition of isostructural thiols and selenols to trimethoxyvinylsilane only the addition products of selenols are formed.

• Research Organization: Irkut-sk Institute of Organic Chemistry (USSR)
• OSTI ID: 5286621
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Vol. 56:8; Other Information: Translated from Zh. Obshch. Khim.; 56: No. 8, 1818-1827(Aug 1986)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ORGANIC IODINE COMPOUNDS
INFRARED SPECTRA
NMR SPECTRA
PHOTOCHEMICAL REACTIONS
SYNTHESIS
SELENIUM COMPLEXES
SILICON COMPLEXES
THIOLS
CATALYTIC EFFECTS
ALKOXIDES
CARBON TETRACHLORIDE
CHEMICAL SHIFT
CHLOROFORM
DEUTERIUM COMPOUNDS
HYDROGEN 1
IODIDES
MOLECULAR STRUCTURE
SELENIDES
STEREOCHEMISTRY
TOXICITY
CHALCOGENIDES
CHEMICAL REACTIONS
CHLORINATED ALIPHATIC HYDROCARBONS
COMPLEXES
HALIDES
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
IODINE COMPOUNDS
ISOTOPES
LIGHT NUCLEI
NUCLEI
ODD-EVEN NUCLEI
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
SELENIUM COMPOUNDS
SPECTRA
STABLE ISOTOPES
400201* - Chemical & Physicochemical Properties
400500 - Photochemistry