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Title: Demonstration of a hydration process for reactivating partially sulfated limestone sorbents

Technical Report ·
OSTI ID:5279467

The utilization of limestione sorbent for the removal of SO/sub 2/ in coal combustion in an atmospheric fluidized-bed combustor (AFBC) can be markedly increased by reactivating the partially sulfated limestone for reuse in the combustor. Such reuse would reduce costs and the environmental impact of quarrying and disposing of large quantities of limestone. The reactivation process consists of hydrating the partially sulfated limestone by treatment with water. A demonstration of the hydration process and the reuse of the reactivated limestone were carried out at Grand Forks Energy Technology Center (GFETC) in cooperation with Argonne National Laboratory (ANL). The data obtained in the GFETC 0.2-m/sup 2/ AFBC are compared with those obtained earlier in the ANL 0.02-m/sup 2/ AFBC. Marked enhancement of calcium utilization was achieved in both studies, but differences were noted in the degree of enhancement and in the Ca/S mole ratios required to maintain SO/sub 2/ in the off-gas at an acceptable level.

Research Organization:
Argonne National Lab., IL (USA)
DOE Contract Number:
W-31-109-ENG-38
OSTI ID:
5279467
Report Number(s):
ANL/CEN/FE-80-23; ON: DE82019236
Country of Publication:
United States
Language:
English