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Title: A study of the growth and decay of cigarette smoke NOx in ambient air under controlled conditions

Abstract

The amount of NO{sub 2} and NO produced by the machine smoking of cigarettes was determined for 15 commercial Canadian brands. Average yield of NO was 1.44 {mu}moles or about 13% of the average reported for American cigarettes. Levels of NO{sub 2} were all less than 12% of NO and were probably due to the oxidation of NO. In order to assess the contribution of tobacco smoke to levels of NO in ambient air, 5 brands of cigarettes were smoked in a 27 cubic meter controlled environment room. Ventilation conditions were either 2.5 or 5.0 air changes per hour (ACH) and each experiment was replicated 3 times for a total of 30 experiments. Ventilation rates of 0.3 and 1.5 ACH were also selected in a second series of experiments in which only one brand of cigarette was smoked. Least squares estimates for the effective ventilation rates were obtained in the usual manner after linearizing the decay portion of the NO time curve. In each of the experiments, the regression explained at least 95% of the variation in the levels of NO with time. Loss of NO due to factors other than ventilation appeared to be constant within experimental error andmore » averaged 2.22 ACH. Equilibrium values for NO were grossly underestimated when results from currently accepted procedures for smoke analysis were used in modeling the growth and decay of NO. Goodness-of-fit was improved when equilibrium values were estimated based on observed levels in ambient air.« less

Authors:
;  [1];  [2]
  1. Labstat Inc., Kitchener, Ontario (Canada)
  2. Environmental Health Centre, Health and Welfare Canada, Ottawa, Ontario (Canada)
Publication Date:
OSTI Identifier:
5231613
Resource Type:
Journal Article
Journal Name:
Environment International; (USA)
Additional Journal Information:
Journal Volume: 13:6; Journal ID: ISSN 0160-4120
Country of Publication:
United States
Language:
English
Subject:
54 ENVIRONMENTAL SCIENCES; INDOOR AIR POLLUTION; NITROGEN OXIDES; AIR POLLUTION MONITORING; TOBACCO SMOKES; CHEMICAL COMPOSITION; EXPERIMENTAL DATA; AEROSOLS; AIR POLLUTION; CHALCOGENIDES; COLLOIDS; DATA; DISPERSIONS; INFORMATION; NITROGEN COMPOUNDS; NUMERICAL DATA; OXIDES; OXYGEN COMPOUNDS; POLLUTION; RESIDUES; SMOKES; SOLS; 540120* - Environment, Atmospheric- Chemicals Monitoring & Transport- (1990-)

Citation Formats

Rickert, W S, Robinson, J C, and Collishaw, N E. A study of the growth and decay of cigarette smoke NOx in ambient air under controlled conditions. United States: N. p., 1987. Web. doi:10.1016/0160-4120(87)90003-1.
Rickert, W S, Robinson, J C, & Collishaw, N E. A study of the growth and decay of cigarette smoke NOx in ambient air under controlled conditions. United States. https://doi.org/10.1016/0160-4120(87)90003-1
Rickert, W S, Robinson, J C, and Collishaw, N E. 1987. "A study of the growth and decay of cigarette smoke NOx in ambient air under controlled conditions". United States. https://doi.org/10.1016/0160-4120(87)90003-1.
@article{osti_5231613,
title = {A study of the growth and decay of cigarette smoke NOx in ambient air under controlled conditions},
author = {Rickert, W S and Robinson, J C and Collishaw, N E},
abstractNote = {The amount of NO{sub 2} and NO produced by the machine smoking of cigarettes was determined for 15 commercial Canadian brands. Average yield of NO was 1.44 {mu}moles or about 13% of the average reported for American cigarettes. Levels of NO{sub 2} were all less than 12% of NO and were probably due to the oxidation of NO. In order to assess the contribution of tobacco smoke to levels of NO in ambient air, 5 brands of cigarettes were smoked in a 27 cubic meter controlled environment room. Ventilation conditions were either 2.5 or 5.0 air changes per hour (ACH) and each experiment was replicated 3 times for a total of 30 experiments. Ventilation rates of 0.3 and 1.5 ACH were also selected in a second series of experiments in which only one brand of cigarette was smoked. Least squares estimates for the effective ventilation rates were obtained in the usual manner after linearizing the decay portion of the NO time curve. In each of the experiments, the regression explained at least 95% of the variation in the levels of NO with time. Loss of NO due to factors other than ventilation appeared to be constant within experimental error and averaged 2.22 ACH. Equilibrium values for NO were grossly underestimated when results from currently accepted procedures for smoke analysis were used in modeling the growth and decay of NO. Goodness-of-fit was improved when equilibrium values were estimated based on observed levels in ambient air.},
doi = {10.1016/0160-4120(87)90003-1},
url = {https://www.osti.gov/biblio/5231613}, journal = {Environment International; (USA)},
issn = {0160-4120},
number = ,
volume = 13:6,
place = {United States},
year = {Thu Jan 01 00:00:00 EST 1987},
month = {Thu Jan 01 00:00:00 EST 1987}
}