Preventing gravel pack and formation dissolution during steam injection
Gravel pack and formation dissolution during steam injection can cause well failures and formation damage. Silicate minerals dissolve in the hot alkaline water injected with steam. This paper describes the use of ammonium salts in preventing dissolution by reducing the pH of generator effluents from 11 and greater to values between 9 and 10. These salts, such as ammonium chloride and ammonium nitrate, do not significantly effect feedwater pH; rather, they reduce effluent pH by decomposing during steam generation to neutralize the alkalinity yielded by bicarbonate decomposition. This process is also described in U.S. Patent No. 4,475,595. Silica dissolution was investigated by flowing both liquid and vapor through tubes packed with gravel. In one case, dissolution from a consolidated core in hot alkaline water was also studied. These tests demonstrate the the effectiveness of ammonium salts in controlling pH and reducing gravel dissolution. Both ammonium chloride and ammonium nitrate have been field tested in steam generators. Ammonium nitrate was added to feedwater at a central facility to determine the simultaneous effect of treatment at five generators operating under different conditions. These tests show that treatment with NH/sub 4/NO/sub 3/ controlled pH within acceptable limits at all generators.
- Research Organization:
- Union Oil Co. of California
- OSTI ID:
- 5199129
- Report Number(s):
- CONF-830512-
- Journal Information:
- Soc. Pet. Eng. AIME, Pap.; (United States), Vol. SPE13660; Conference: IEE/APS symposium, Houston, TX, USA, 23 May 1983
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
DISPLACEMENT FLUIDS
ROCK-FLUID INTERACTIONS
OIL WELLS
STEAM INJECTION
RESERVOIR ROCK
DISSOLUTION
AMMONIUM CHLORIDES
AMMONIUM NITRATES
PACKINGS
PH VALUE
SILICA
SILICATES
THERMAL RECOVERY
AMMONIUM COMPOUNDS
AMMONIUM HALIDES
CHALCOGENIDES
CHLORIDES
CHLORINE COMPOUNDS
ENHANCED RECOVERY
FLUID INJECTION
FLUIDS
HALIDES
HALOGEN COMPOUNDS
MINERALS
NITRATES
NITROGEN COMPOUNDS
OXIDE MINERALS
OXIDES
OXYGEN COMPOUNDS
RECOVERY
SILICON COMPOUNDS
SILICON OXIDES
WELLS
020300* - Petroleum- Drilling & Production