Shock-wave response of titanium subhydride-potassium perchlorate
Shock initiation of pyrotechnic materials is becoming increasingly more interesting since this concept is now used in weapon component design. In this study we have performed several types of shock initiation experiments on TiH/sub 0/ /sub 65//KC10/sub 4/ to better understand its shock response and the process by which it undergoes reaction. Gas gun impact experiments have led to new unreacted Hugoniot information which was used, along with earlier reported data, to construct an equation of state for the unreacted material. Particle velocity records of the projectile impact interface and the shock transmitted through the sample show little evidence of reaction in the first microsecond even for 6 GPa shocks. Peculiarities in the waveforms at later times suggest some evidence of reaction although the experiments do not remain strictly one-dimensional long enough to make definite statements. Flyer plate initiated compacts indicate a short input pulse is rapidly attenuated but the material is initiated and a combustion wave propagates through the compact at velocities of about 0.4 to 0.7 km/s.
- Research Organization:
- Sandia National Labs., Albuquerque, NM (USA)
- DOE Contract Number:
- AC04-76DP00789
- OSTI ID:
- 5182528
- Report Number(s):
- SAND-82-0489C; CONF-820710-9; ON: DE82016739
- Resource Relation:
- Conference: 8. international pyrotechnics symposium, Steamboat Springs, CO, USA, 12 Jul 1982
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
CHEMICAL EXPLOSIVES
COMPACTING
DETONATIONS
PHYSICAL PROPERTIES
SHOCK WAVES
WAVE PROPAGATION
CHLORATES
EQUATIONS OF STATE
EXPERIMENTAL DATA
IMPACT SHOCK
POTASSIUM COMPOUNDS
TITANIUM HYDRIDES
ALKALI METAL COMPOUNDS
CHLORINE COMPOUNDS
DATA
EQUATIONS
EXPLOSIVES
HALOGEN COMPOUNDS
HYDRIDES
HYDROGEN COMPOUNDS
INFORMATION
NUMERICAL DATA
OXYGEN COMPOUNDS
TITANIUM COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
450100* - Military Technology
Weaponry
& National Defense- Chemical Explosions & Explosives