Synthetic design of MLCT excited states. Ligand-substituted, mono-2,2'-bipyridine complexes of Ru(II)
Journal Article
·
· Journal of the American Chemical Society; (USA)
The role of the 2,2'-bipyridine ligand in metal to ligand charge transfer (MLCT) excited states and of the effect of substituent changes on that role has been investigated by spectroscopic and photochemical measurements on the series ((tpm)Ru(4,4'-(X){sub 2}-2,2'-bipyridine)(py)){sup 2+} (X = C(O)OC{sub 2}H{sub 5}, C{sub 6}H{sub 5}, CH{sub 3}, NH{sub 2}, H; tpm is tris(1-pyrazolyl)methane). 65 refs., 8 figs., 4 tabs.
- DOE Contract Number:
- FG05-86ER13633
- OSTI ID:
- 5174636
- Journal Information:
- Journal of the American Chemical Society; (USA), Vol. 110:23; ISSN 0002-7863
- Country of Publication:
- United States
- Language:
- English
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OSTI ID:5174636
Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
BIPYRIDINES
EXCITED STATES
ORGANOMETALLIC COMPOUNDS
RUTHENIUM COMPOUNDS
EXPERIMENTAL DATA
AZINES
DATA
ENERGY LEVELS
HETEROCYCLIC COMPOUNDS
INFORMATION
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PYRIDINES
REFRACTORY METAL COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
400201* - Chemical & Physicochemical Properties
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
BIPYRIDINES
EXCITED STATES
ORGANOMETALLIC COMPOUNDS
RUTHENIUM COMPOUNDS
EXPERIMENTAL DATA
AZINES
DATA
ENERGY LEVELS
HETEROCYCLIC COMPOUNDS
INFORMATION
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PYRIDINES
REFRACTORY METAL COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
400201* - Chemical & Physicochemical Properties