Primary tritium isotope effect on hydride transfer from sodium borohydride to cyclopropenium ion
Journal Article
·
· J. Org. Chem.; (United States)
Reduction of a cyclopropenium perchlorate with tritium-labeled sodium borohydride shows a primary kinetic isotope effect, suggesting that hydride transfer is at least partially rate-determining and thus demonstrating that formation of the encounter complex between cation and hydride is reversible.
- Research Organization:
- Oregon State Univ., Corvallis
- OSTI ID:
- 5130239
- Journal Information:
- J. Org. Chem.; (United States), Vol. 45:13
- Country of Publication:
- United States
- Language:
- English
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Fri Jan 30 00:00:00 EST 1981
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Journal Article
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· J. Am. Chem. Soc.; (United States)
·
OSTI ID:5130239
Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
TRITIUM
ISOTOPE EFFECTS
BOROHYDRIDES
CARBOXYLIC ACIDS
CATIONS
CYCLOALKENES
HYDRIDES
KINETICS
PERCHLORATES
REDUCTION
SODIUM COMPOUNDS
ALKALI METAL COMPOUNDS
ALKENES
BETA DECAY RADIOISOTOPES
BETA-MINUS DECAY RADIOISOTOPES
BORON COMPOUNDS
CHARGED PARTICLES
CHEMICAL REACTIONS
CHLORINE COMPOUNDS
HALOGEN COMPOUNDS
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
IONS
ISOTOPES
LIGHT NUCLEI
NUCLEI
ODD-EVEN NUCLEI
ORGANIC ACIDS
ORGANIC COMPOUNDS
OXYGEN COMPOUNDS
RADIOISOTOPES
YEARS LIVING RADIOISOTOPES
400302* - Organic Chemistry- Isotope Effects- (-1987)
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
TRITIUM
ISOTOPE EFFECTS
BOROHYDRIDES
CARBOXYLIC ACIDS
CATIONS
CYCLOALKENES
HYDRIDES
KINETICS
PERCHLORATES
REDUCTION
SODIUM COMPOUNDS
ALKALI METAL COMPOUNDS
ALKENES
BETA DECAY RADIOISOTOPES
BETA-MINUS DECAY RADIOISOTOPES
BORON COMPOUNDS
CHARGED PARTICLES
CHEMICAL REACTIONS
CHLORINE COMPOUNDS
HALOGEN COMPOUNDS
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
IONS
ISOTOPES
LIGHT NUCLEI
NUCLEI
ODD-EVEN NUCLEI
ORGANIC ACIDS
ORGANIC COMPOUNDS
OXYGEN COMPOUNDS
RADIOISOTOPES
YEARS LIVING RADIOISOTOPES
400302* - Organic Chemistry- Isotope Effects- (-1987)