Hydrogermylation of itaconic and sorbic derivatives

Journal Article · Sat Oct 10 00:00:00 EDT 1987 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5129324

Gar, T K; Viktorov, N A; Nosova, V M; Kisin, A V; Ivashchenko, D A; Popkov, M K; Mironov, V F

We have investigated the reactions of trichlorogermane with itaconic acid and its derivatives and also with derivatives of sorbic acid. It was shown that the acid chlorides and the anhydride of itaconic acid readily undergo addition with the trichlorogermane ether complex. The structures of the compounds obtained were determined by means of /sup 1/H and /sup 13/C NMR spectroscopy with the use of model compounds: 3-butenoyl chloride, methyl 3-butenoate, crotonoyl chloride, methyl crotonate, and products of the addition of trichlorogermane ether complex to the latter.

• Research Organization: State Research Institute of the Chemistry and Technology of Organometallic Compounds, Moscow (USSR)
• OSTI ID: 5129324
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Vol. 57:4; Other Information: Translated from Zh. Obshch. Khim.; 57: No. 4, 871-879(Apr 1987)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
74 ATOMIC AND MOLECULAR PHYSICS
GERMANIUM COMPLEXES
NMR SPECTRA
SYNTHESIS
GERMANIUM COMPOUNDS
COMPLEXOMETRY
ITACONIC ACID
SORBIC ACID
CARBON 13
CHEMICAL SHIFT
CHLOROFORM
DEUTERIUM COMPOUNDS
HYDROGEN 1
HYPERFINE STRUCTURE
ISOMERIZATION
MOLECULAR STRUCTURE
MULTIPLETS
CARBON ISOTOPES
CARBOXYLIC ACIDS
CHEMICAL REACTIONS
CHLORINATED ALIPHATIC HYDROCARBONS
COMPLEXES
DICARBOXYLIC ACIDS
EVEN-ODD NUCLEI
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
ISOTOPES
LIGHT NUCLEI
MONOCARBOXYLIC ACIDS
NUCLEI
ODD-EVEN NUCLEI
ORGANIC ACIDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
SPECTRA
STABLE ISOTOPES
400201* - Chemical & Physicochemical Properties
640302 - Atomic
Molecular & Chemical Physics- Atomic & Molecular Properties & Theory